{1-[1-(3-Carboxy­propanamido)eth­yl]-1′,2-bis­(diphenyl­phosphino)ferrocene-κ(2) P,P′}dichloridoplatinum(II) dichloro­methane 1.25-solvate

The dinuclear title compound, [FePtCl(2)(C(17)H(14)P)(C(23)H(23)NO(3)P)]·1.25CH(2)Cl(2), has a slightly distorted cis-PtCl(2)P(2) square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2)° about Pt. In the crystal structure, the complex form...

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Autores principales: Spencer, Lara C., Bjelosevic, Haris, Darkwa, James, Elmroth, Sofi K. C., Persson, Tina
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915101/
https://www.ncbi.nlm.nih.gov/pubmed/21200513
http://dx.doi.org/10.1107/S1600536807065105
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author Spencer, Lara C.
Bjelosevic, Haris
Darkwa, James
Elmroth, Sofi K. C.
Persson, Tina
author_facet Spencer, Lara C.
Bjelosevic, Haris
Darkwa, James
Elmroth, Sofi K. C.
Persson, Tina
author_sort Spencer, Lara C.
collection PubMed
description The dinuclear title compound, [FePtCl(2)(C(17)H(14)P)(C(23)H(23)NO(3)P)]·1.25CH(2)Cl(2), has a slightly distorted cis-PtCl(2)P(2) square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2)° about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong inter­molecular O—H⋯O bonds resulting in R (2) (2)(8) rings. A weak intra­molecular N—H⋯Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms.
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spelling pubmed-29151012010-12-30 {1-[1-(3-Carboxy­propanamido)eth­yl]-1′,2-bis­(diphenyl­phosphino)ferrocene-κ(2) P,P′}dichloridoplatinum(II) dichloro­methane 1.25-solvate Spencer, Lara C. Bjelosevic, Haris Darkwa, James Elmroth, Sofi K. C. Persson, Tina Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title compound, [FePtCl(2)(C(17)H(14)P)(C(23)H(23)NO(3)P)]·1.25CH(2)Cl(2), has a slightly distorted cis-PtCl(2)P(2) square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2)° about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong inter­molecular O—H⋯O bonds resulting in R (2) (2)(8) rings. A weak intra­molecular N—H⋯Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915101/ /pubmed/21200513 http://dx.doi.org/10.1107/S1600536807065105 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Spencer, Lara C.
Bjelosevic, Haris
Darkwa, James
Elmroth, Sofi K. C.
Persson, Tina
{1-[1-(3-Carboxy­propanamido)eth­yl]-1′,2-bis­(diphenyl­phosphino)ferrocene-κ(2) P,P′}dichloridoplatinum(II) dichloro­methane 1.25-solvate
title {1-[1-(3-Carboxy­propanamido)eth­yl]-1′,2-bis­(diphenyl­phosphino)ferrocene-κ(2) P,P′}dichloridoplatinum(II) dichloro­methane 1.25-solvate
title_full {1-[1-(3-Carboxy­propanamido)eth­yl]-1′,2-bis­(diphenyl­phosphino)ferrocene-κ(2) P,P′}dichloridoplatinum(II) dichloro­methane 1.25-solvate
title_fullStr {1-[1-(3-Carboxy­propanamido)eth­yl]-1′,2-bis­(diphenyl­phosphino)ferrocene-κ(2) P,P′}dichloridoplatinum(II) dichloro­methane 1.25-solvate
title_full_unstemmed {1-[1-(3-Carboxy­propanamido)eth­yl]-1′,2-bis­(diphenyl­phosphino)ferrocene-κ(2) P,P′}dichloridoplatinum(II) dichloro­methane 1.25-solvate
title_short {1-[1-(3-Carboxy­propanamido)eth­yl]-1′,2-bis­(diphenyl­phosphino)ferrocene-κ(2) P,P′}dichloridoplatinum(II) dichloro­methane 1.25-solvate
title_sort {1-[1-(3-carboxy­propanamido)eth­yl]-1′,2-bis­(diphenyl­phosphino)ferrocene-κ(2) p,p′}dichloridoplatinum(ii) dichloro­methane 1.25-solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915101/
https://www.ncbi.nlm.nih.gov/pubmed/21200513
http://dx.doi.org/10.1107/S1600536807065105
work_keys_str_mv AT spencerlarac 113carboxypropanamidoethyl12bisdiphenylphosphinoferrocenek2ppdichloridoplatinumiidichloromethane125solvate
AT bjelosevicharis 113carboxypropanamidoethyl12bisdiphenylphosphinoferrocenek2ppdichloridoplatinumiidichloromethane125solvate
AT darkwajames 113carboxypropanamidoethyl12bisdiphenylphosphinoferrocenek2ppdichloridoplatinumiidichloromethane125solvate
AT elmrothsofikc 113carboxypropanamidoethyl12bisdiphenylphosphinoferrocenek2ppdichloridoplatinumiidichloromethane125solvate
AT perssontina 113carboxypropanamidoethyl12bisdiphenylphosphinoferrocenek2ppdichloridoplatinumiidichloromethane125solvate

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