Bis(μ-carboxyl­atoethyl­phospho­nato)bis­[aqua­(2,2′-bipyridine)manganese(II)]

The title compound, [Mn(2)(HO(3)PCH(2)CH(2)COO)(2)(C(8)H(8)N(2))(2)(H(2)O)(2)], was obtained by hydro­thermal synthesis. The manganese(II) ions are six-coordinate and are linked by two 2-carboxy­ethyl­phospho­nate ligands, forming a centrosymmetric dimer. The Mn ions adopts a distorted octahedral co...

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Detalles Bibliográficos
Autores principales: Ying, Shao-Ming, Chen, Yun, Luo, Qiu-Yan, Xv, Ya-Ping, Liu, Dong-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915102/
https://www.ncbi.nlm.nih.gov/pubmed/21200514
http://dx.doi.org/10.1107/S1600536807065142
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author Ying, Shao-Ming
Chen, Yun
Luo, Qiu-Yan
Xv, Ya-Ping
Liu, Dong-Sheng
author_facet Ying, Shao-Ming
Chen, Yun
Luo, Qiu-Yan
Xv, Ya-Ping
Liu, Dong-Sheng
author_sort Ying, Shao-Ming
collection PubMed
description The title compound, [Mn(2)(HO(3)PCH(2)CH(2)COO)(2)(C(8)H(8)N(2))(2)(H(2)O)(2)], was obtained by hydro­thermal synthesis. The manganese(II) ions are six-coordinate and are linked by two 2-carboxy­ethyl­phospho­nate ligands, forming a centrosymmetric dimer. The Mn ions adopts a distorted octahedral coordination geometry. The dimers are further linked by O—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance 4.2754 (4) Å].
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spelling pubmed-29151022010-12-30 Bis(μ-carboxyl­atoethyl­phospho­nato)bis­[aqua­(2,2′-bipyridine)manganese(II)] Ying, Shao-Ming Chen, Yun Luo, Qiu-Yan Xv, Ya-Ping Liu, Dong-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(2)(HO(3)PCH(2)CH(2)COO)(2)(C(8)H(8)N(2))(2)(H(2)O)(2)], was obtained by hydro­thermal synthesis. The manganese(II) ions are six-coordinate and are linked by two 2-carboxy­ethyl­phospho­nate ligands, forming a centrosymmetric dimer. The Mn ions adopts a distorted octahedral coordination geometry. The dimers are further linked by O—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance 4.2754 (4) Å]. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915102/ /pubmed/21200514 http://dx.doi.org/10.1107/S1600536807065142 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Ying, Shao-Ming
Chen, Yun
Luo, Qiu-Yan
Xv, Ya-Ping
Liu, Dong-Sheng
Bis(μ-carboxyl­atoethyl­phospho­nato)bis­[aqua­(2,2′-bipyridine)manganese(II)]
title Bis(μ-carboxyl­atoethyl­phospho­nato)bis­[aqua­(2,2′-bipyridine)manganese(II)]
title_full Bis(μ-carboxyl­atoethyl­phospho­nato)bis­[aqua­(2,2′-bipyridine)manganese(II)]
title_fullStr Bis(μ-carboxyl­atoethyl­phospho­nato)bis­[aqua­(2,2′-bipyridine)manganese(II)]
title_full_unstemmed Bis(μ-carboxyl­atoethyl­phospho­nato)bis­[aqua­(2,2′-bipyridine)manganese(II)]
title_short Bis(μ-carboxyl­atoethyl­phospho­nato)bis­[aqua­(2,2′-bipyridine)manganese(II)]
title_sort bis(μ-carboxyl­atoethyl­phospho­nato)bis­[aqua­(2,2′-bipyridine)manganese(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915102/
https://www.ncbi.nlm.nih.gov/pubmed/21200514
http://dx.doi.org/10.1107/S1600536807065142
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