Doxofyllinium tetra­chloridoanti­monate(III) monohydrate

The title compound, (C(11)H(14)N(4)O(4))[SbCl(4)]·H(2)O, comprises a protonated doxofyllinium cation [7-(1,3-dioxolan-2-ylmeth­yl)-1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ium], an [SbCl(4)](−) anion and a water mol­ecule linked by N—H⋯O and O—H⋯Cl hydrogen bonds: the [SbCl(4)](−) anions form c...

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Detalles Bibliográficos
Autores principales: Wei, Wan Xing, Feng, Wen-Jie, Zheng, Bo-Jiöng, Chen, Ying, Jin, Zhi-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915103/
https://www.ncbi.nlm.nih.gov/pubmed/21200515
http://dx.doi.org/10.1107/S1600536807065774
Descripción
Sumario:The title compound, (C(11)H(14)N(4)O(4))[SbCl(4)]·H(2)O, comprises a protonated doxofyllinium cation [7-(1,3-dioxolan-2-ylmeth­yl)-1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ium], an [SbCl(4)](−) anion and a water mol­ecule linked by N—H⋯O and O—H⋯Cl hydrogen bonds: the [SbCl(4)](−) anions form centrosymmetric dimers via weak Sb⋯Cl inter­actions [Sb⋯Cl = 3.1159 (9) Å]. The geometrical arrangement in the crystal structure is characterized by slipped π–π stacking of the parallel purine ring systems, with an inter­planar separation of 3.32 Å.

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