Bis(nona­fluoro­butane­sulfonato-κO)dioxidotris(tetra­hydro­furan-κO)uranium(VI)

In the title compound, [U(C(4)F(9)O(3)S)O(2)(C(4)H(8)O)(3)], each U(VI) ion is located on a twofold rotation axis and is seven-coordinated by two terminal O atoms in the axial positions [U—O = 1.737 (5) Å] and five O atoms from two monodentate nona­fluoro­butane­sulfonate (NfO(−)) and three tetra­hy...

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Detalles Bibliográficos
Autores principales: Takao, Koichiro, Ikeda, Yasuhisa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915104/
https://www.ncbi.nlm.nih.gov/pubmed/21200516
http://dx.doi.org/10.1107/S1600536807065865
Descripción
Sumario:In the title compound, [U(C(4)F(9)O(3)S)O(2)(C(4)H(8)O)(3)], each U(VI) ion is located on a twofold rotation axis and is seven-coordinated by two terminal O atoms in the axial positions [U—O = 1.737 (5) Å] and five O atoms from two monodentate nona­fluoro­butane­sulfonate (NfO(−)) and three tetra­hydro­furan ligands in the equatorial plane [U—O = 2.388 (5)–2.411 (4) Å] in a penta­gonal–bipyramidal geometry. The crystal packing exhibits weak inter­molecular C—H⋯O hydrogen bonds involving the non-coordinated O atoms of the NfO(−) ligands.

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