Bis(nona­fluoro­butane­sulfonato-κO)dioxidotris(tetra­hydro­furan-κO)uranium(VI)

In the title compound, [U(C(4)F(9)O(3)S)O(2)(C(4)H(8)O)(3)], each U(VI) ion is located on a twofold rotation axis and is seven-coordinated by two terminal O atoms in the axial positions [U—O = 1.737 (5) Å] and five O atoms from two monodentate nona­fluoro­butane­sulfonate (NfO(−)) and three tetra­hy...

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Detalles Bibliográficos
Autores principales: Takao, Koichiro, Ikeda, Yasuhisa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915104/
https://www.ncbi.nlm.nih.gov/pubmed/21200516
http://dx.doi.org/10.1107/S1600536807065865
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author Takao, Koichiro
Ikeda, Yasuhisa
author_facet Takao, Koichiro
Ikeda, Yasuhisa
author_sort Takao, Koichiro
collection PubMed
description In the title compound, [U(C(4)F(9)O(3)S)O(2)(C(4)H(8)O)(3)], each U(VI) ion is located on a twofold rotation axis and is seven-coordinated by two terminal O atoms in the axial positions [U—O = 1.737 (5) Å] and five O atoms from two monodentate nona­fluoro­butane­sulfonate (NfO(−)) and three tetra­hydro­furan ligands in the equatorial plane [U—O = 2.388 (5)–2.411 (4) Å] in a penta­gonal–bipyramidal geometry. The crystal packing exhibits weak inter­molecular C—H⋯O hydrogen bonds involving the non-coordinated O atoms of the NfO(−) ligands.
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spelling pubmed-29151042010-12-30 Bis(nona­fluoro­butane­sulfonato-κO)dioxidotris(tetra­hydro­furan-κO)uranium(VI) Takao, Koichiro Ikeda, Yasuhisa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [U(C(4)F(9)O(3)S)O(2)(C(4)H(8)O)(3)], each U(VI) ion is located on a twofold rotation axis and is seven-coordinated by two terminal O atoms in the axial positions [U—O = 1.737 (5) Å] and five O atoms from two monodentate nona­fluoro­butane­sulfonate (NfO(−)) and three tetra­hydro­furan ligands in the equatorial plane [U—O = 2.388 (5)–2.411 (4) Å] in a penta­gonal–bipyramidal geometry. The crystal packing exhibits weak inter­molecular C—H⋯O hydrogen bonds involving the non-coordinated O atoms of the NfO(−) ligands. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915104/ /pubmed/21200516 http://dx.doi.org/10.1107/S1600536807065865 Text en © Takao and Ikeda 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Takao, Koichiro
Ikeda, Yasuhisa
Bis(nona­fluoro­butane­sulfonato-κO)dioxidotris(tetra­hydro­furan-κO)uranium(VI)
title Bis(nona­fluoro­butane­sulfonato-κO)dioxidotris(tetra­hydro­furan-κO)uranium(VI)
title_full Bis(nona­fluoro­butane­sulfonato-κO)dioxidotris(tetra­hydro­furan-κO)uranium(VI)
title_fullStr Bis(nona­fluoro­butane­sulfonato-κO)dioxidotris(tetra­hydro­furan-κO)uranium(VI)
title_full_unstemmed Bis(nona­fluoro­butane­sulfonato-κO)dioxidotris(tetra­hydro­furan-κO)uranium(VI)
title_short Bis(nona­fluoro­butane­sulfonato-κO)dioxidotris(tetra­hydro­furan-κO)uranium(VI)
title_sort bis(nona­fluoro­butane­sulfonato-κo)dioxidotris(tetra­hydro­furan-κo)uranium(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915104/
https://www.ncbi.nlm.nih.gov/pubmed/21200516
http://dx.doi.org/10.1107/S1600536807065865
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AT ikedayasuhisa bisnonafluorobutanesulfonatokodioxidotristetrahydrofurankouraniumvi

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