Poly[[di-μ(4)-4,4′-oxydiphthalato-tetrakis[μ(2)-1,1′-(p-phenyl­enedimethyl­ene)di-1H-imidazole]tetra­copper(II)] monohydrate]

In the title compound, {[Cu(4)(C(16)H(6)O(9))(2)(C(14)H(14)N(4))(4)]·H(2)O}(n), the water mol­ecule is disordered over two positions; site-occupancy factors were fixed at 0.25. The Cu(II) atom exhibits a square-planar coordination geometry with two O atoms of the two 4,4′-oxydiphthalate ligands and...

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Detalles Bibliográficos
Autores principales: Zhang, Wu, Yao, Li, Tao, Ruojie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915105/
https://www.ncbi.nlm.nih.gov/pubmed/21200517
http://dx.doi.org/10.1107/S1600536807065713
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author Zhang, Wu
Yao, Li
Tao, Ruojie
author_facet Zhang, Wu
Yao, Li
Tao, Ruojie
author_sort Zhang, Wu
collection PubMed
description In the title compound, {[Cu(4)(C(16)H(6)O(9))(2)(C(14)H(14)N(4))(4)]·H(2)O}(n), the water mol­ecule is disordered over two positions; site-occupancy factors were fixed at 0.25. The Cu(II) atom exhibits a square-planar coordination geometry with two O atoms of the two 4,4′-oxydiphthalate ligands and two N atoms of the two 1,4-bis­(imidazol-1-ylmeth­yl)benzene groups. A three-dimensional honeycomb framework structure is formed. Aromatic π–π stacking inter­actions are observed, with a centroid–centroid distance of 3.373 (5) Å.
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spelling pubmed-29151052010-12-30 Poly[[di-μ(4)-4,4′-oxydiphthalato-tetrakis[μ(2)-1,1′-(p-phenyl­enedimethyl­ene)di-1H-imidazole]tetra­copper(II)] monohydrate] Zhang, Wu Yao, Li Tao, Ruojie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(4)(C(16)H(6)O(9))(2)(C(14)H(14)N(4))(4)]·H(2)O}(n), the water mol­ecule is disordered over two positions; site-occupancy factors were fixed at 0.25. The Cu(II) atom exhibits a square-planar coordination geometry with two O atoms of the two 4,4′-oxydiphthalate ligands and two N atoms of the two 1,4-bis­(imidazol-1-ylmeth­yl)benzene groups. A three-dimensional honeycomb framework structure is formed. Aromatic π–π stacking inter­actions are observed, with a centroid–centroid distance of 3.373 (5) Å. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915105/ /pubmed/21200517 http://dx.doi.org/10.1107/S1600536807065713 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Zhang, Wu
Yao, Li
Tao, Ruojie
Poly[[di-μ(4)-4,4′-oxydiphthalato-tetrakis[μ(2)-1,1′-(p-phenyl­enedimethyl­ene)di-1H-imidazole]tetra­copper(II)] monohydrate]
title Poly[[di-μ(4)-4,4′-oxydiphthalato-tetrakis[μ(2)-1,1′-(p-phenyl­enedimethyl­ene)di-1H-imidazole]tetra­copper(II)] monohydrate]
title_full Poly[[di-μ(4)-4,4′-oxydiphthalato-tetrakis[μ(2)-1,1′-(p-phenyl­enedimethyl­ene)di-1H-imidazole]tetra­copper(II)] monohydrate]
title_fullStr Poly[[di-μ(4)-4,4′-oxydiphthalato-tetrakis[μ(2)-1,1′-(p-phenyl­enedimethyl­ene)di-1H-imidazole]tetra­copper(II)] monohydrate]
title_full_unstemmed Poly[[di-μ(4)-4,4′-oxydiphthalato-tetrakis[μ(2)-1,1′-(p-phenyl­enedimethyl­ene)di-1H-imidazole]tetra­copper(II)] monohydrate]
title_short Poly[[di-μ(4)-4,4′-oxydiphthalato-tetrakis[μ(2)-1,1′-(p-phenyl­enedimethyl­ene)di-1H-imidazole]tetra­copper(II)] monohydrate]
title_sort poly[[di-μ(4)-4,4′-oxydiphthalato-tetrakis[μ(2)-1,1′-(p-phenyl­enedimethyl­ene)di-1h-imidazole]tetra­copper(ii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915105/
https://www.ncbi.nlm.nih.gov/pubmed/21200517
http://dx.doi.org/10.1107/S1600536807065713
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AT yaoli polydim444oxydiphthalatotetrakism211pphenylenedimethylenedi1himidazoletetracopperiimonohydrate
AT taoruojie polydim444oxydiphthalatotetrakism211pphenylenedimethylenedi1himidazoletetracopperiimonohydrate

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