Oxalatobis(propane-1,3-diamine)manganese(II) chloride monohydrate

In the asymmetric unit of the title compound, [Mn(C(2)O(4))(C(3)H(10)N(2))(2)]Cl·H(2)O, there are two independent Mn(III) complexes, two Cl(−) anions and two uncoordinated water mol­ecules. Each Mn(III) atom is hexa­coordinated by four N atoms from two propane-1,3-diamine ligands and two O atoms fro...

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Detalles Bibliográficos
Autores principales: Meng, Qing-Guo, Wang, Lin-Tong, Liu, Yan-Zhen, Pang, Yan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915106/
https://www.ncbi.nlm.nih.gov/pubmed/21200519
http://dx.doi.org/10.1107/S1600536807065361
Descripción
Sumario:In the asymmetric unit of the title compound, [Mn(C(2)O(4))(C(3)H(10)N(2))(2)]Cl·H(2)O, there are two independent Mn(III) complexes, two Cl(−) anions and two uncoordinated water mol­ecules. Each Mn(III) atom is hexa­coordinated by four N atoms from two propane-1,3-diamine ligands and two O atoms from one oxalate ligand, resulting in a slightly distorted octa­hedral MnO(2)N(4) geometry. Mn—O and Mn—N bond lengths are in the ranges 1.969 (2)–2.020 (3) and 2.068 (3)–2.113 (4) Å, respectively. There are weak inter­molecular O—H⋯O, O—H⋯Cl, N—H⋯O and N—H⋯Cl hydrogen bonds with D⋯A distances in the range 2.831 (4)–3.423 (3) Å.

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