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Oxalatobis(propane-1,3-diamine)manganese(II) chloride monohydrate
In the asymmetric unit of the title compound, [Mn(C(2)O(4))(C(3)H(10)N(2))(2)]Cl·H(2)O, there are two independent Mn(III) complexes, two Cl(−) anions and two uncoordinated water molecules. Each Mn(III) atom is hexacoordinated by four N atoms from two propane-1,3-diamine ligands and two O atoms fro...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915106/ https://www.ncbi.nlm.nih.gov/pubmed/21200519 http://dx.doi.org/10.1107/S1600536807065361 |
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author | Meng, Qing-Guo Wang, Lin-Tong Liu, Yan-Zhen Pang, Yan |
author_facet | Meng, Qing-Guo Wang, Lin-Tong Liu, Yan-Zhen Pang, Yan |
author_sort | Meng, Qing-Guo |
collection | PubMed |
description | In the asymmetric unit of the title compound, [Mn(C(2)O(4))(C(3)H(10)N(2))(2)]Cl·H(2)O, there are two independent Mn(III) complexes, two Cl(−) anions and two uncoordinated water molecules. Each Mn(III) atom is hexacoordinated by four N atoms from two propane-1,3-diamine ligands and two O atoms from one oxalate ligand, resulting in a slightly distorted octahedral MnO(2)N(4) geometry. Mn—O and Mn—N bond lengths are in the ranges 1.969 (2)–2.020 (3) and 2.068 (3)–2.113 (4) Å, respectively. There are weak intermolecular O—H⋯O, O—H⋯Cl, N—H⋯O and N—H⋯Cl hydrogen bonds with D⋯A distances in the range 2.831 (4)–3.423 (3) Å. |
format | Text |
id | pubmed-2915106 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29151062010-12-30 Oxalatobis(propane-1,3-diamine)manganese(II) chloride monohydrate Meng, Qing-Guo Wang, Lin-Tong Liu, Yan-Zhen Pang, Yan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the asymmetric unit of the title compound, [Mn(C(2)O(4))(C(3)H(10)N(2))(2)]Cl·H(2)O, there are two independent Mn(III) complexes, two Cl(−) anions and two uncoordinated water molecules. Each Mn(III) atom is hexacoordinated by four N atoms from two propane-1,3-diamine ligands and two O atoms from one oxalate ligand, resulting in a slightly distorted octahedral MnO(2)N(4) geometry. Mn—O and Mn—N bond lengths are in the ranges 1.969 (2)–2.020 (3) and 2.068 (3)–2.113 (4) Å, respectively. There are weak intermolecular O—H⋯O, O—H⋯Cl, N—H⋯O and N—H⋯Cl hydrogen bonds with D⋯A distances in the range 2.831 (4)–3.423 (3) Å. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915106/ /pubmed/21200519 http://dx.doi.org/10.1107/S1600536807065361 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Meng, Qing-Guo Wang, Lin-Tong Liu, Yan-Zhen Pang, Yan Oxalatobis(propane-1,3-diamine)manganese(II) chloride monohydrate |
title | Oxalatobis(propane-1,3-diamine)manganese(II) chloride monohydrate |
title_full | Oxalatobis(propane-1,3-diamine)manganese(II) chloride monohydrate |
title_fullStr | Oxalatobis(propane-1,3-diamine)manganese(II) chloride monohydrate |
title_full_unstemmed | Oxalatobis(propane-1,3-diamine)manganese(II) chloride monohydrate |
title_short | Oxalatobis(propane-1,3-diamine)manganese(II) chloride monohydrate |
title_sort | oxalatobis(propane-1,3-diamine)manganese(ii) chloride monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915106/ https://www.ncbi.nlm.nih.gov/pubmed/21200519 http://dx.doi.org/10.1107/S1600536807065361 |
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