N′-Ferrocenyl-2-hydroxy­benzohydrazide

The title complex, [Fe(C(5)H(5))(C(13)H(11)N(2)O(3))], was prepared via self-assembly using ferrocenyl hydrazide and ethyl salicylate. The compound is potentially a tridentate ferrocene-based ligand. The conformation of the mol­ecule allows the formation of an intra­molecular N—H⋯O hydrogen bond inv...

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Detalles Bibliográficos
Autores principales: Xu, Ying, Chen, Chun-Ling, Zhou, Jing, Li, Ming-Xue
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915112/
https://www.ncbi.nlm.nih.gov/pubmed/21200525
http://dx.doi.org/10.1107/S1600536807065634
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author Xu, Ying
Chen, Chun-Ling
Zhou, Jing
Li, Ming-Xue
author_facet Xu, Ying
Chen, Chun-Ling
Zhou, Jing
Li, Ming-Xue
author_sort Xu, Ying
collection PubMed
description The title complex, [Fe(C(5)H(5))(C(13)H(11)N(2)O(3))], was prepared via self-assembly using ferrocenyl hydrazide and ethyl salicylate. The compound is potentially a tridentate ferrocene-based ligand. The conformation of the mol­ecule allows the formation of an intra­molecular N—H⋯O hydrogen bond involving the hydroxyl group. The CONHNHCO unit and the rings bonded to it are nearly coplanar. The crystal structure is stabilized by inter­molecular O—H⋯O(carbon­yl) and N—H⋯O(carbon­yl) hydrogen bonds.
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spelling pubmed-29151122010-12-30 N′-Ferrocenyl-2-hydroxy­benzohydrazide Xu, Ying Chen, Chun-Ling Zhou, Jing Li, Ming-Xue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Fe(C(5)H(5))(C(13)H(11)N(2)O(3))], was prepared via self-assembly using ferrocenyl hydrazide and ethyl salicylate. The compound is potentially a tridentate ferrocene-based ligand. The conformation of the mol­ecule allows the formation of an intra­molecular N—H⋯O hydrogen bond involving the hydroxyl group. The CONHNHCO unit and the rings bonded to it are nearly coplanar. The crystal structure is stabilized by inter­molecular O—H⋯O(carbon­yl) and N—H⋯O(carbon­yl) hydrogen bonds. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915112/ /pubmed/21200525 http://dx.doi.org/10.1107/S1600536807065634 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Xu, Ying
Chen, Chun-Ling
Zhou, Jing
Li, Ming-Xue
N′-Ferrocenyl-2-hydroxy­benzohydrazide
title N′-Ferrocenyl-2-hydroxy­benzohydrazide
title_full N′-Ferrocenyl-2-hydroxy­benzohydrazide
title_fullStr N′-Ferrocenyl-2-hydroxy­benzohydrazide
title_full_unstemmed N′-Ferrocenyl-2-hydroxy­benzohydrazide
title_short N′-Ferrocenyl-2-hydroxy­benzohydrazide
title_sort n′-ferrocenyl-2-hydroxy­benzohydrazide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915112/
https://www.ncbi.nlm.nih.gov/pubmed/21200525
http://dx.doi.org/10.1107/S1600536807065634
work_keys_str_mv AT xuying nferrocenyl2hydroxybenzohydrazide
AT chenchunling nferrocenyl2hydroxybenzohydrazide
AT zhoujing nferrocenyl2hydroxybenzohydrazide
AT limingxue nferrocenyl2hydroxybenzohydrazide

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