trans-Carbonyl­chloridobis(ethyl­diphenyl­phosphine-κP)rhodium(I)

The title compound, [RhCl(C(14)H(15)P)(2)(CO)], crystallizes with two almost identical mol­ecules in the asymmetric unit. The mol­ecules have the Rh(I) atom in a square-planar geometry. The crystal structure involves intermolecular C—H⋯O hydrogen bonds.

Detalles Bibliográficos
Autores principales: Lorenzini, Fabio, Patrick, Brian O., James, Brian R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915114/
https://www.ncbi.nlm.nih.gov/pubmed/21200527
http://dx.doi.org/10.1107/S1600536807065877
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author Lorenzini, Fabio
Patrick, Brian O.
James, Brian R.
author_facet Lorenzini, Fabio
Patrick, Brian O.
James, Brian R.
author_sort Lorenzini, Fabio
collection PubMed
description The title compound, [RhCl(C(14)H(15)P)(2)(CO)], crystallizes with two almost identical mol­ecules in the asymmetric unit. The mol­ecules have the Rh(I) atom in a square-planar geometry. The crystal structure involves intermolecular C—H⋯O hydrogen bonds.
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spelling pubmed-29151142010-12-30 trans-Carbonyl­chloridobis(ethyl­diphenyl­phosphine-κP)rhodium(I) Lorenzini, Fabio Patrick, Brian O. James, Brian R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [RhCl(C(14)H(15)P)(2)(CO)], crystallizes with two almost identical mol­ecules in the asymmetric unit. The mol­ecules have the Rh(I) atom in a square-planar geometry. The crystal structure involves intermolecular C—H⋯O hydrogen bonds. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915114/ /pubmed/21200527 http://dx.doi.org/10.1107/S1600536807065877 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Lorenzini, Fabio
Patrick, Brian O.
James, Brian R.
trans-Carbonyl­chloridobis(ethyl­diphenyl­phosphine-κP)rhodium(I)
title trans-Carbonyl­chloridobis(ethyl­diphenyl­phosphine-κP)rhodium(I)
title_full trans-Carbonyl­chloridobis(ethyl­diphenyl­phosphine-κP)rhodium(I)
title_fullStr trans-Carbonyl­chloridobis(ethyl­diphenyl­phosphine-κP)rhodium(I)
title_full_unstemmed trans-Carbonyl­chloridobis(ethyl­diphenyl­phosphine-κP)rhodium(I)
title_short trans-Carbonyl­chloridobis(ethyl­diphenyl­phosphine-κP)rhodium(I)
title_sort trans-carbonyl­chloridobis(ethyl­diphenyl­phosphine-κp)rhodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915114/
https://www.ncbi.nlm.nih.gov/pubmed/21200527
http://dx.doi.org/10.1107/S1600536807065877
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AT patrickbriano transcarbonylchloridobisethyldiphenylphosphinekprhodiumi
AT jamesbrianr transcarbonylchloridobisethyldiphenylphosphinekprhodiumi

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