Bis[2-(2-amino­ethyl)-1H-benzimidazole-κ(2) N (2),N (3)]zinc(II) bis­(perchlorate)

In the title compound, [Zn(C(9)H(11)N(3))(2)](ClO(4))(2), the Zn(II) atom resides on a crystallographic twofold axis and is coordinated by two benzimidazole N [Zn⋯N = 1.993 (4) Å] and two amine N atoms [Zn⋯N = 2.036 (4) Å] in a distorted tetra­hedral geometry. The crystal packing is dominated by N—H...

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Detalles Bibliográficos
Autores principales: Zhang, Jine, Li, Yanping, Huo, Fangjun, Zhang, Zhigang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915116/
https://www.ncbi.nlm.nih.gov/pubmed/21200530
http://dx.doi.org/10.1107/S160053680706610X
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author Zhang, Jine
Li, Yanping
Huo, Fangjun
Zhang, Zhigang
author_facet Zhang, Jine
Li, Yanping
Huo, Fangjun
Zhang, Zhigang
author_sort Zhang, Jine
collection PubMed
description In the title compound, [Zn(C(9)H(11)N(3))(2)](ClO(4))(2), the Zn(II) atom resides on a crystallographic twofold axis and is coordinated by two benzimidazole N [Zn⋯N = 1.993 (4) Å] and two amine N atoms [Zn⋯N = 2.036 (4) Å] in a distorted tetra­hedral geometry. The crystal packing is dominated by N—H⋯O inter­actions involving the perchlorate anions and π–π stacking inter­actions with an inter­planar separation of 3.42 Å. A weak C—H⋯O inter­action is also present.
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spelling pubmed-29151162010-12-30 Bis[2-(2-amino­ethyl)-1H-benzimidazole-κ(2) N (2),N (3)]zinc(II) bis­(perchlorate) Zhang, Jine Li, Yanping Huo, Fangjun Zhang, Zhigang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(9)H(11)N(3))(2)](ClO(4))(2), the Zn(II) atom resides on a crystallographic twofold axis and is coordinated by two benzimidazole N [Zn⋯N = 1.993 (4) Å] and two amine N atoms [Zn⋯N = 2.036 (4) Å] in a distorted tetra­hedral geometry. The crystal packing is dominated by N—H⋯O inter­actions involving the perchlorate anions and π–π stacking inter­actions with an inter­planar separation of 3.42 Å. A weak C—H⋯O inter­action is also present. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915116/ /pubmed/21200530 http://dx.doi.org/10.1107/S160053680706610X Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Zhang, Jine
Li, Yanping
Huo, Fangjun
Zhang, Zhigang
Bis[2-(2-amino­ethyl)-1H-benzimidazole-κ(2) N (2),N (3)]zinc(II) bis­(perchlorate)
title Bis[2-(2-amino­ethyl)-1H-benzimidazole-κ(2) N (2),N (3)]zinc(II) bis­(perchlorate)
title_full Bis[2-(2-amino­ethyl)-1H-benzimidazole-κ(2) N (2),N (3)]zinc(II) bis­(perchlorate)
title_fullStr Bis[2-(2-amino­ethyl)-1H-benzimidazole-κ(2) N (2),N (3)]zinc(II) bis­(perchlorate)
title_full_unstemmed Bis[2-(2-amino­ethyl)-1H-benzimidazole-κ(2) N (2),N (3)]zinc(II) bis­(perchlorate)
title_short Bis[2-(2-amino­ethyl)-1H-benzimidazole-κ(2) N (2),N (3)]zinc(II) bis­(perchlorate)
title_sort bis[2-(2-amino­ethyl)-1h-benzimidazole-κ(2) n (2),n (3)]zinc(ii) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915116/
https://www.ncbi.nlm.nih.gov/pubmed/21200530
http://dx.doi.org/10.1107/S160053680706610X
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AT liyanping bis22aminoethyl1hbenzimidazolek2n2n3zinciibisperchlorate
AT huofangjun bis22aminoethyl1hbenzimidazolek2n2n3zinciibisperchlorate
AT zhangzhigang bis22aminoethyl1hbenzimidazolek2n2n3zinciibisperchlorate

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