cis-cis-trans-Bis(acetonitrile-κN)dichloridobis(triphenyl­phosphine-κP)ruthenium(II) acetonitrile disolvate

The title compound, [RuCl(2)(C(2)H(3)N)(2)(C(18)H(15)P)(2)]·2C(2)H(3)N, was obtained upon stirring an acetonitrile/ethanol solution of [RuCl(2)(PPh(3))(3)]. In the crystal structure, each Ru(II) ion is coordinated by two Cl [Ru—Cl = 2.4308 (7) and 2.4139 (7) Å], two N [Ru—N = 2.016 (2) and 2.003 (2)...

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Detalles Bibliográficos
Autores principales: Al-Far, Ahmad M., Slaughter, LeGrande M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915117/
https://www.ncbi.nlm.nih.gov/pubmed/21200532
http://dx.doi.org/10.1107/S1600536807065968
Descripción
Sumario:The title compound, [RuCl(2)(C(2)H(3)N)(2)(C(18)H(15)P)(2)]·2C(2)H(3)N, was obtained upon stirring an acetonitrile/ethanol solution of [RuCl(2)(PPh(3))(3)]. In the crystal structure, each Ru(II) ion is coordinated by two Cl [Ru—Cl = 2.4308 (7) and 2.4139 (7) Å], two N [Ru—N = 2.016 (2) and 2.003 (2) Å], and two P [Ru—P = 2.3688 (7) and 2.3887 (7) Å] atoms in a distorted octa­hedral geometry. Packing inter­actions include typical C—H⋯π contacts involving phenyl groups as well as weak hydrogen bonds between CH(3)CN methyl H atoms and Cl or solvent CH(3)CN N atoms.

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