catena-Poly[[bis­(N,N′-dimethyl­formamide)cadmium(II)]-μ(2)-oxalato]

The title compound, [Cd(C(2)O(4))(C(3)H(7)NO)(2)](n), is isostructural with its Mn(II) analogue. The structure comprises zigzag polymeric chains with the oxalate groups situated on inversion centres and the Cd(II) atoms located on twofold rotation axes. The coordination geometry around Cd(II) is dis...

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Detalles Bibliográficos
Autores principales: Borel, Cédric, Langer, Vratislav, Arnehed, Johan, Leikvoll, Lisette, Ghazzali, Mohamed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915118/
https://www.ncbi.nlm.nih.gov/pubmed/21200533
http://dx.doi.org/10.1107/S1600536807066147
Descripción
Sumario:The title compound, [Cd(C(2)O(4))(C(3)H(7)NO)(2)](n), is isostructural with its Mn(II) analogue. The structure comprises zigzag polymeric chains with the oxalate groups situated on inversion centres and the Cd(II) atoms located on twofold rotation axes. The coordination geometry around Cd(II) is distorted octa­hedral and the intra­chain Cd⋯Cd distance is 5.842 (1) Å. C—H⋯O hydrogen bonds exist between the parallel polymeric chains.

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