catena-Poly[[bis­(N,N′-dimethyl­formamide)cadmium(II)]-μ(2)-oxalato]

The title compound, [Cd(C(2)O(4))(C(3)H(7)NO)(2)](n), is isostructural with its Mn(II) analogue. The structure comprises zigzag polymeric chains with the oxalate groups situated on inversion centres and the Cd(II) atoms located on twofold rotation axes. The coordination geometry around Cd(II) is dis...

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Detalles Bibliográficos
Autores principales: Borel, Cédric, Langer, Vratislav, Arnehed, Johan, Leikvoll, Lisette, Ghazzali, Mohamed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915118/
https://www.ncbi.nlm.nih.gov/pubmed/21200533
http://dx.doi.org/10.1107/S1600536807066147
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author Borel, Cédric
Langer, Vratislav
Arnehed, Johan
Leikvoll, Lisette
Ghazzali, Mohamed
author_facet Borel, Cédric
Langer, Vratislav
Arnehed, Johan
Leikvoll, Lisette
Ghazzali, Mohamed
author_sort Borel, Cédric
collection PubMed
description The title compound, [Cd(C(2)O(4))(C(3)H(7)NO)(2)](n), is isostructural with its Mn(II) analogue. The structure comprises zigzag polymeric chains with the oxalate groups situated on inversion centres and the Cd(II) atoms located on twofold rotation axes. The coordination geometry around Cd(II) is distorted octa­hedral and the intra­chain Cd⋯Cd distance is 5.842 (1) Å. C—H⋯O hydrogen bonds exist between the parallel polymeric chains.
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spelling pubmed-29151182010-12-30 catena-Poly[[bis­(N,N′-dimethyl­formamide)cadmium(II)]-μ(2)-oxalato] Borel, Cédric Langer, Vratislav Arnehed, Johan Leikvoll, Lisette Ghazzali, Mohamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(C(2)O(4))(C(3)H(7)NO)(2)](n), is isostructural with its Mn(II) analogue. The structure comprises zigzag polymeric chains with the oxalate groups situated on inversion centres and the Cd(II) atoms located on twofold rotation axes. The coordination geometry around Cd(II) is distorted octa­hedral and the intra­chain Cd⋯Cd distance is 5.842 (1) Å. C—H⋯O hydrogen bonds exist between the parallel polymeric chains. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915118/ /pubmed/21200533 http://dx.doi.org/10.1107/S1600536807066147 Text en © Borel et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Borel, Cédric
Langer, Vratislav
Arnehed, Johan
Leikvoll, Lisette
Ghazzali, Mohamed
catena-Poly[[bis­(N,N′-dimethyl­formamide)cadmium(II)]-μ(2)-oxalato]
title catena-Poly[[bis­(N,N′-dimethyl­formamide)cadmium(II)]-μ(2)-oxalato]
title_full catena-Poly[[bis­(N,N′-dimethyl­formamide)cadmium(II)]-μ(2)-oxalato]
title_fullStr catena-Poly[[bis­(N,N′-dimethyl­formamide)cadmium(II)]-μ(2)-oxalato]
title_full_unstemmed catena-Poly[[bis­(N,N′-dimethyl­formamide)cadmium(II)]-μ(2)-oxalato]
title_short catena-Poly[[bis­(N,N′-dimethyl­formamide)cadmium(II)]-μ(2)-oxalato]
title_sort catena-poly[[bis­(n,n′-dimethyl­formamide)cadmium(ii)]-μ(2)-oxalato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915118/
https://www.ncbi.nlm.nih.gov/pubmed/21200533
http://dx.doi.org/10.1107/S1600536807066147
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