Bis[bis­(1H-benzimidazol-2-ylmeth­yl)amine]copper(II) dichloride methanol disolvate dihydrate

In the title compound, [Cu(C(16)H(14)N(5))(2)]Cl(2)·2CH(4)O·2H(2)O, the cationic metal complex resides on a crystallographic centre of inversion, with the Cu(2+) bonded to two bis­(1H-benzimidazol-2-ylmeth­yl)amines (IDB). The coordination geometry of the Cu(2+) ion is distorted octa­hedral with an...

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Detalles Bibliográficos
Autores principales: Xia, Xian-you, Zhang, Yong, Qu, Yuan, Chen, Xue-mei, Liu, Ting
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915122/
https://www.ncbi.nlm.nih.gov/pubmed/21200538
http://dx.doi.org/10.1107/S1600536807065816
Descripción
Sumario:In the title compound, [Cu(C(16)H(14)N(5))(2)]Cl(2)·2CH(4)O·2H(2)O, the cationic metal complex resides on a crystallographic centre of inversion, with the Cu(2+) bonded to two bis­(1H-benzimidazol-2-ylmeth­yl)amines (IDB). The coordination geometry of the Cu(2+) ion is distorted octa­hedral with an N(6) ligand set. A three-dimensional framework structure is formed by means of hydrogen bonds and π–π inter­actions formed between imidazole and phenyl rings, and between phenyl and phenyl rings, with centroid-to-centroid distances of 3.690 (2)–3.977 (2) Å and interplanar spacings of 3.445 (2)–3.502 (2) Å.

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