Bis[bis­(1H-benzimidazol-2-ylmeth­yl)amine]copper(II) dichloride methanol disolvate dihydrate

In the title compound, [Cu(C(16)H(14)N(5))(2)]Cl(2)·2CH(4)O·2H(2)O, the cationic metal complex resides on a crystallographic centre of inversion, with the Cu(2+) bonded to two bis­(1H-benzimidazol-2-ylmeth­yl)amines (IDB). The coordination geometry of the Cu(2+) ion is distorted octa­hedral with an...

Descripción completa

Detalles Bibliográficos
Autores principales: Xia, Xian-you, Zhang, Yong, Qu, Yuan, Chen, Xue-mei, Liu, Ting
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915122/
https://www.ncbi.nlm.nih.gov/pubmed/21200538
http://dx.doi.org/10.1107/S1600536807065816
_version_ 1782184865417920512
author Xia, Xian-you
Zhang, Yong
Qu, Yuan
Chen, Xue-mei
Liu, Ting
author_facet Xia, Xian-you
Zhang, Yong
Qu, Yuan
Chen, Xue-mei
Liu, Ting
author_sort Xia, Xian-you
collection PubMed
description In the title compound, [Cu(C(16)H(14)N(5))(2)]Cl(2)·2CH(4)O·2H(2)O, the cationic metal complex resides on a crystallographic centre of inversion, with the Cu(2+) bonded to two bis­(1H-benzimidazol-2-ylmeth­yl)amines (IDB). The coordination geometry of the Cu(2+) ion is distorted octa­hedral with an N(6) ligand set. A three-dimensional framework structure is formed by means of hydrogen bonds and π–π inter­actions formed between imidazole and phenyl rings, and between phenyl and phenyl rings, with centroid-to-centroid distances of 3.690 (2)–3.977 (2) Å and interplanar spacings of 3.445 (2)–3.502 (2) Å.
format Text
id pubmed-2915122
institution National Center for Biotechnology Information
language English
publishDate 2007
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29151222010-12-30 Bis[bis­(1H-benzimidazol-2-ylmeth­yl)amine]copper(II) dichloride methanol disolvate dihydrate Xia, Xian-you Zhang, Yong Qu, Yuan Chen, Xue-mei Liu, Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(16)H(14)N(5))(2)]Cl(2)·2CH(4)O·2H(2)O, the cationic metal complex resides on a crystallographic centre of inversion, with the Cu(2+) bonded to two bis­(1H-benzimidazol-2-ylmeth­yl)amines (IDB). The coordination geometry of the Cu(2+) ion is distorted octa­hedral with an N(6) ligand set. A three-dimensional framework structure is formed by means of hydrogen bonds and π–π inter­actions formed between imidazole and phenyl rings, and between phenyl and phenyl rings, with centroid-to-centroid distances of 3.690 (2)–3.977 (2) Å and interplanar spacings of 3.445 (2)–3.502 (2) Å. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915122/ /pubmed/21200538 http://dx.doi.org/10.1107/S1600536807065816 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Xia, Xian-you
Zhang, Yong
Qu, Yuan
Chen, Xue-mei
Liu, Ting
Bis[bis­(1H-benzimidazol-2-ylmeth­yl)amine]copper(II) dichloride methanol disolvate dihydrate
title Bis[bis­(1H-benzimidazol-2-ylmeth­yl)amine]copper(II) dichloride methanol disolvate dihydrate
title_full Bis[bis­(1H-benzimidazol-2-ylmeth­yl)amine]copper(II) dichloride methanol disolvate dihydrate
title_fullStr Bis[bis­(1H-benzimidazol-2-ylmeth­yl)amine]copper(II) dichloride methanol disolvate dihydrate
title_full_unstemmed Bis[bis­(1H-benzimidazol-2-ylmeth­yl)amine]copper(II) dichloride methanol disolvate dihydrate
title_short Bis[bis­(1H-benzimidazol-2-ylmeth­yl)amine]copper(II) dichloride methanol disolvate dihydrate
title_sort bis[bis­(1h-benzimidazol-2-ylmeth­yl)amine]copper(ii) dichloride methanol disolvate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915122/
https://www.ncbi.nlm.nih.gov/pubmed/21200538
http://dx.doi.org/10.1107/S1600536807065816
work_keys_str_mv AT xiaxianyou bisbis1hbenzimidazol2ylmethylaminecopperiidichloridemethanoldisolvatedihydrate
AT zhangyong bisbis1hbenzimidazol2ylmethylaminecopperiidichloridemethanoldisolvatedihydrate
AT quyuan bisbis1hbenzimidazol2ylmethylaminecopperiidichloridemethanoldisolvatedihydrate
AT chenxuemei bisbis1hbenzimidazol2ylmethylaminecopperiidichloridemethanoldisolvatedihydrate
AT liuting bisbis1hbenzimidazol2ylmethylaminecopperiidichloridemethanoldisolvatedihydrate

Ejemplares similares