{Bis[2-(diphenyl­phosphan­yl)phen­yl] ether-κ(2) P,P′}(1,1′-dibenz­yl-1H,1′H-4,4′bi-1,2,3-triazole-κ(2) N(3),N (3′))copper(I) hexa­fluorido­phosphate dichloro­methane hemisolvate

In the crystal structure of the title compound, [Cu(C(18)H(16)N(6))(C(36)H(28)OP(2))]PF(6)·0.5CH(2)Cl(2) or [Cu(DPEPhos)(Bn-bta)]PF(6)·0.5CH(2)Cl(2) {DPEPhos = bis­[(diphenyl­phosphan­yl)phen­yl] ether and Bn-bta = 1,1′-dibenzyl-1H,1′H-4,4′-bi-1,2,3triazol­e}, the Cu atom is coordinated by two N and...

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Detalles Bibliográficos
Autores principales: Monkowius, Uwe, Ritter, Stefan, König, Burkhard, Yersin, Hartmut, Zabel, Manfred
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915126/
https://www.ncbi.nlm.nih.gov/pubmed/21200542
http://dx.doi.org/10.1107/S1600536807066342
Descripción
Sumario:In the crystal structure of the title compound, [Cu(C(18)H(16)N(6))(C(36)H(28)OP(2))]PF(6)·0.5CH(2)Cl(2) or [Cu(DPEPhos)(Bn-bta)]PF(6)·0.5CH(2)Cl(2) {DPEPhos = bis­[(diphenyl­phosphan­yl)phen­yl] ether and Bn-bta = 1,1′-dibenzyl-1H,1′H-4,4′-bi-1,2,3triazol­e}, the Cu atom is coordinated by two N and two P atoms of the ligands in a strongly distorted tetra­hedral environment. There are two crystallographically independent complex cations present, which differ significantly in their geometrical parameters. The solvent molecule is disordered but satisfactory atomic positions could not be determined.

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