{Bis[2-(diphenyl­phosphan­yl)phen­yl] ether-κ(2) P,P′}(1,1′-dibenz­yl-1H,1′H-4,4′bi-1,2,3-triazole-κ(2) N(3),N (3′))copper(I) hexa­fluorido­phosphate dichloro­methane hemisolvate

In the crystal structure of the title compound, [Cu(C(18)H(16)N(6))(C(36)H(28)OP(2))]PF(6)·0.5CH(2)Cl(2) or [Cu(DPEPhos)(Bn-bta)]PF(6)·0.5CH(2)Cl(2) {DPEPhos = bis­[(diphenyl­phosphan­yl)phen­yl] ether and Bn-bta = 1,1′-dibenzyl-1H,1′H-4,4′-bi-1,2,3triazol­e}, the Cu atom is coordinated by two N and...

Descripción completa

Detalles Bibliográficos
Autores principales: Monkowius, Uwe, Ritter, Stefan, König, Burkhard, Yersin, Hartmut, Zabel, Manfred
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915126/
https://www.ncbi.nlm.nih.gov/pubmed/21200542
http://dx.doi.org/10.1107/S1600536807066342
_version_ 1782184866368978944
author Monkowius, Uwe
Ritter, Stefan
König, Burkhard
Yersin, Hartmut
Zabel, Manfred
author_facet Monkowius, Uwe
Ritter, Stefan
König, Burkhard
Yersin, Hartmut
Zabel, Manfred
author_sort Monkowius, Uwe
collection PubMed
description In the crystal structure of the title compound, [Cu(C(18)H(16)N(6))(C(36)H(28)OP(2))]PF(6)·0.5CH(2)Cl(2) or [Cu(DPEPhos)(Bn-bta)]PF(6)·0.5CH(2)Cl(2) {DPEPhos = bis­[(diphenyl­phosphan­yl)phen­yl] ether and Bn-bta = 1,1′-dibenzyl-1H,1′H-4,4′-bi-1,2,3triazol­e}, the Cu atom is coordinated by two N and two P atoms of the ligands in a strongly distorted tetra­hedral environment. There are two crystallographically independent complex cations present, which differ significantly in their geometrical parameters. The solvent molecule is disordered but satisfactory atomic positions could not be determined.
format Text
id pubmed-2915126
institution National Center for Biotechnology Information
language English
publishDate 2007
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29151262010-12-30 {Bis[2-(diphenyl­phosphan­yl)phen­yl] ether-κ(2) P,P′}(1,1′-dibenz­yl-1H,1′H-4,4′bi-1,2,3-triazole-κ(2) N(3),N (3′))copper(I) hexa­fluorido­phosphate dichloro­methane hemisolvate Monkowius, Uwe Ritter, Stefan König, Burkhard Yersin, Hartmut Zabel, Manfred Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(C(18)H(16)N(6))(C(36)H(28)OP(2))]PF(6)·0.5CH(2)Cl(2) or [Cu(DPEPhos)(Bn-bta)]PF(6)·0.5CH(2)Cl(2) {DPEPhos = bis­[(diphenyl­phosphan­yl)phen­yl] ether and Bn-bta = 1,1′-dibenzyl-1H,1′H-4,4′-bi-1,2,3triazol­e}, the Cu atom is coordinated by two N and two P atoms of the ligands in a strongly distorted tetra­hedral environment. There are two crystallographically independent complex cations present, which differ significantly in their geometrical parameters. The solvent molecule is disordered but satisfactory atomic positions could not be determined. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915126/ /pubmed/21200542 http://dx.doi.org/10.1107/S1600536807066342 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Monkowius, Uwe
Ritter, Stefan
König, Burkhard
Yersin, Hartmut
Zabel, Manfred
{Bis[2-(diphenyl­phosphan­yl)phen­yl] ether-κ(2) P,P′}(1,1′-dibenz­yl-1H,1′H-4,4′bi-1,2,3-triazole-κ(2) N(3),N (3′))copper(I) hexa­fluorido­phosphate dichloro­methane hemisolvate
title {Bis[2-(diphenyl­phosphan­yl)phen­yl] ether-κ(2) P,P′}(1,1′-dibenz­yl-1H,1′H-4,4′bi-1,2,3-triazole-κ(2) N(3),N (3′))copper(I) hexa­fluorido­phosphate dichloro­methane hemisolvate
title_full {Bis[2-(diphenyl­phosphan­yl)phen­yl] ether-κ(2) P,P′}(1,1′-dibenz­yl-1H,1′H-4,4′bi-1,2,3-triazole-κ(2) N(3),N (3′))copper(I) hexa­fluorido­phosphate dichloro­methane hemisolvate
title_fullStr {Bis[2-(diphenyl­phosphan­yl)phen­yl] ether-κ(2) P,P′}(1,1′-dibenz­yl-1H,1′H-4,4′bi-1,2,3-triazole-κ(2) N(3),N (3′))copper(I) hexa­fluorido­phosphate dichloro­methane hemisolvate
title_full_unstemmed {Bis[2-(diphenyl­phosphan­yl)phen­yl] ether-κ(2) P,P′}(1,1′-dibenz­yl-1H,1′H-4,4′bi-1,2,3-triazole-κ(2) N(3),N (3′))copper(I) hexa­fluorido­phosphate dichloro­methane hemisolvate
title_short {Bis[2-(diphenyl­phosphan­yl)phen­yl] ether-κ(2) P,P′}(1,1′-dibenz­yl-1H,1′H-4,4′bi-1,2,3-triazole-κ(2) N(3),N (3′))copper(I) hexa­fluorido­phosphate dichloro­methane hemisolvate
title_sort {bis[2-(diphenyl­phosphan­yl)phen­yl] ether-κ(2) p,p′}(1,1′-dibenz­yl-1h,1′h-4,4′bi-1,2,3-triazole-κ(2) n(3),n (3′))copper(i) hexa­fluorido­phosphate dichloro­methane hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915126/
https://www.ncbi.nlm.nih.gov/pubmed/21200542
http://dx.doi.org/10.1107/S1600536807066342
work_keys_str_mv AT monkowiusuwe bis2diphenylphosphanylphenyletherk2pp11dibenzyl1h1h44bi123triazolek2n3n3copperihexafluoridophosphatedichloromethanehemisolvate
AT ritterstefan bis2diphenylphosphanylphenyletherk2pp11dibenzyl1h1h44bi123triazolek2n3n3copperihexafluoridophosphatedichloromethanehemisolvate
AT konigburkhard bis2diphenylphosphanylphenyletherk2pp11dibenzyl1h1h44bi123triazolek2n3n3copperihexafluoridophosphatedichloromethanehemisolvate
AT yersinhartmut bis2diphenylphosphanylphenyletherk2pp11dibenzyl1h1h44bi123triazolek2n3n3copperihexafluoridophosphatedichloromethanehemisolvate
AT zabelmanfred bis2diphenylphosphanylphenyletherk2pp11dibenzyl1h1h44bi123triazolek2n3n3copperihexafluoridophosphatedichloromethanehemisolvate

Ejemplares similares