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Di-μ(3)-oxido-bis­(μ(2)-quinaldato-κ(2) O:O)­bis­(quinaldato-κ(2) N,O)tetra­kis[di-n-butyl­tin(IV)]

The title tetra­nuclear Sn(IV) complex, [Sn(4)(C(4)H(9))(8)(C(10)H(6)NO(2))(4)O(2)], is a cluster built up by inversion symmetry around the central Sn(2)O(2) ring. The coordination geometries of the Sn atoms involved can be classified into two types: the five-coordinate Sn atoms of the central Sn(2)...

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Detalles Bibliográficos
Autores principales: Wang, Hongyun, Yin, Handong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915128/
https://www.ncbi.nlm.nih.gov/pubmed/21200544
http://dx.doi.org/10.1107/S1600536807066378
Descripción
Sumario:The title tetra­nuclear Sn(IV) complex, [Sn(4)(C(4)H(9))(8)(C(10)H(6)NO(2))(4)O(2)], is a cluster built up by inversion symmetry around the central Sn(2)O(2) ring. The coordination geometries of the Sn atoms involved can be classified into two types: the five-coordinate Sn atoms of the central Sn(2)O(2) core have a trigonal–bipyramidal geometry, with axial positions occupied by a μ(3)-O atom and a μ(2)-O atom belonging to the nonchelating quinaldate ligand. The peripheral Sn atoms are six-coordinate, with a distorted octa­hedral geometry. The methyl group of an n-butyl ligand is disordered over two sites, with occupancies of 0.643 (12) and 0.357 (12).