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Di-μ(3)-oxido-bis(μ(2)-quinaldato-κ(2) O:O)bis(quinaldato-κ(2) N,O)tetrakis[di-n-butyltin(IV)]
The title tetranuclear Sn(IV) complex, [Sn(4)(C(4)H(9))(8)(C(10)H(6)NO(2))(4)O(2)], is a cluster built up by inversion symmetry around the central Sn(2)O(2) ring. The coordination geometries of the Sn atoms involved can be classified into two types: the five-coordinate Sn atoms of the central Sn(2)...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915128/ https://www.ncbi.nlm.nih.gov/pubmed/21200544 http://dx.doi.org/10.1107/S1600536807066378 |
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author | Wang, Hongyun Yin, Handong |
author_facet | Wang, Hongyun Yin, Handong |
author_sort | Wang, Hongyun |
collection | PubMed |
description | The title tetranuclear Sn(IV) complex, [Sn(4)(C(4)H(9))(8)(C(10)H(6)NO(2))(4)O(2)], is a cluster built up by inversion symmetry around the central Sn(2)O(2) ring. The coordination geometries of the Sn atoms involved can be classified into two types: the five-coordinate Sn atoms of the central Sn(2)O(2) core have a trigonal–bipyramidal geometry, with axial positions occupied by a μ(3)-O atom and a μ(2)-O atom belonging to the nonchelating quinaldate ligand. The peripheral Sn atoms are six-coordinate, with a distorted octahedral geometry. The methyl group of an n-butyl ligand is disordered over two sites, with occupancies of 0.643 (12) and 0.357 (12). |
format | Text |
id | pubmed-2915128 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29151282010-12-30 Di-μ(3)-oxido-bis(μ(2)-quinaldato-κ(2) O:O)bis(quinaldato-κ(2) N,O)tetrakis[di-n-butyltin(IV)] Wang, Hongyun Yin, Handong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title tetranuclear Sn(IV) complex, [Sn(4)(C(4)H(9))(8)(C(10)H(6)NO(2))(4)O(2)], is a cluster built up by inversion symmetry around the central Sn(2)O(2) ring. The coordination geometries of the Sn atoms involved can be classified into two types: the five-coordinate Sn atoms of the central Sn(2)O(2) core have a trigonal–bipyramidal geometry, with axial positions occupied by a μ(3)-O atom and a μ(2)-O atom belonging to the nonchelating quinaldate ligand. The peripheral Sn atoms are six-coordinate, with a distorted octahedral geometry. The methyl group of an n-butyl ligand is disordered over two sites, with occupancies of 0.643 (12) and 0.357 (12). International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915128/ /pubmed/21200544 http://dx.doi.org/10.1107/S1600536807066378 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Wang, Hongyun Yin, Handong Di-μ(3)-oxido-bis(μ(2)-quinaldato-κ(2) O:O)bis(quinaldato-κ(2) N,O)tetrakis[di-n-butyltin(IV)] |
title | Di-μ(3)-oxido-bis(μ(2)-quinaldato-κ(2)
O:O)bis(quinaldato-κ(2)
N,O)tetrakis[di-n-butyltin(IV)] |
title_full | Di-μ(3)-oxido-bis(μ(2)-quinaldato-κ(2)
O:O)bis(quinaldato-κ(2)
N,O)tetrakis[di-n-butyltin(IV)] |
title_fullStr | Di-μ(3)-oxido-bis(μ(2)-quinaldato-κ(2)
O:O)bis(quinaldato-κ(2)
N,O)tetrakis[di-n-butyltin(IV)] |
title_full_unstemmed | Di-μ(3)-oxido-bis(μ(2)-quinaldato-κ(2)
O:O)bis(quinaldato-κ(2)
N,O)tetrakis[di-n-butyltin(IV)] |
title_short | Di-μ(3)-oxido-bis(μ(2)-quinaldato-κ(2)
O:O)bis(quinaldato-κ(2)
N,O)tetrakis[di-n-butyltin(IV)] |
title_sort | di-μ(3)-oxido-bis(μ(2)-quinaldato-κ(2)
o:o)bis(quinaldato-κ(2)
n,o)tetrakis[di-n-butyltin(iv)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915128/ https://www.ncbi.nlm.nih.gov/pubmed/21200544 http://dx.doi.org/10.1107/S1600536807066378 |
work_keys_str_mv | AT wanghongyun dim3oxidobism2quinaldatok2oobisquinaldatok2notetrakisdinbutyltiniv AT yinhandong dim3oxidobism2quinaldatok2oobisquinaldatok2notetrakisdinbutyltiniv |