Rhodamine 6G hexa­chlorido­stannate(IV) acetonitrile disolvate

In the title compound, bis({6-ethylamino-10-[2-(methoxycarbonyl)phenyl]-2,7-dimethylxanthen-3-ylidene}ethanaminium) hexachloridotin(IV) acetonitrile disolvate, (C(27)H(29)N(2)O(3))(2)[SnCl(6)]·2C(2)H(3)N, the octa­hedral SnCl(6) (2−) anion lies on an inversion center. The xanthene ring system is ess...

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Detalles Bibliográficos
Autores principales: Venkatraman, Ramaiyer, Sitole, Lungile, Fronczek, Frank R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915129/
https://www.ncbi.nlm.nih.gov/pubmed/21200545
http://dx.doi.org/10.1107/S1600536807066287
Descripción
Sumario:In the title compound, bis({6-ethylamino-10-[2-(methoxycarbonyl)phenyl]-2,7-dimethylxanthen-3-ylidene}ethanaminium) hexachloridotin(IV) acetonitrile disolvate, (C(27)H(29)N(2)O(3))(2)[SnCl(6)]·2C(2)H(3)N, the octa­hedral SnCl(6) (2−) anion lies on an inversion center. The xanthene ring system is essentially planar, with an average deviation of 0.020 Å, and the substituent benzene ring forms a dihedral angle of 85.89 (2)° with it. The Sn—Cl distances are in the range 2.4237 (3)–2.4454 (3) Å. There are N—H⋯Cl hydrogen bonds between SnCl(6) (2−) ions and rhodamine 6G cations as well as π–π stacking inter­actions between rhodamine 6G cations (inter­planar distance of 3.827 Å).

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