Rhodamine 6G hexa­chlorido­stannate(IV) acetonitrile disolvate

In the title compound, bis({6-ethylamino-10-[2-(methoxycarbonyl)phenyl]-2,7-dimethylxanthen-3-ylidene}ethanaminium) hexachloridotin(IV) acetonitrile disolvate, (C(27)H(29)N(2)O(3))(2)[SnCl(6)]·2C(2)H(3)N, the octa­hedral SnCl(6) (2−) anion lies on an inversion center. The xanthene ring system is ess...

Descripción completa

Detalles Bibliográficos
Autores principales: Venkatraman, Ramaiyer, Sitole, Lungile, Fronczek, Frank R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915129/
https://www.ncbi.nlm.nih.gov/pubmed/21200545
http://dx.doi.org/10.1107/S1600536807066287
_version_ 1782184867059990528
author Venkatraman, Ramaiyer
Sitole, Lungile
Fronczek, Frank R.
author_facet Venkatraman, Ramaiyer
Sitole, Lungile
Fronczek, Frank R.
author_sort Venkatraman, Ramaiyer
collection PubMed
description In the title compound, bis({6-ethylamino-10-[2-(methoxycarbonyl)phenyl]-2,7-dimethylxanthen-3-ylidene}ethanaminium) hexachloridotin(IV) acetonitrile disolvate, (C(27)H(29)N(2)O(3))(2)[SnCl(6)]·2C(2)H(3)N, the octa­hedral SnCl(6) (2−) anion lies on an inversion center. The xanthene ring system is essentially planar, with an average deviation of 0.020 Å, and the substituent benzene ring forms a dihedral angle of 85.89 (2)° with it. The Sn—Cl distances are in the range 2.4237 (3)–2.4454 (3) Å. There are N—H⋯Cl hydrogen bonds between SnCl(6) (2−) ions and rhodamine 6G cations as well as π–π stacking inter­actions between rhodamine 6G cations (inter­planar distance of 3.827 Å).
format Text
id pubmed-2915129
institution National Center for Biotechnology Information
language English
publishDate 2007
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29151292010-12-30 Rhodamine 6G hexa­chlorido­stannate(IV) acetonitrile disolvate Venkatraman, Ramaiyer Sitole, Lungile Fronczek, Frank R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, bis({6-ethylamino-10-[2-(methoxycarbonyl)phenyl]-2,7-dimethylxanthen-3-ylidene}ethanaminium) hexachloridotin(IV) acetonitrile disolvate, (C(27)H(29)N(2)O(3))(2)[SnCl(6)]·2C(2)H(3)N, the octa­hedral SnCl(6) (2−) anion lies on an inversion center. The xanthene ring system is essentially planar, with an average deviation of 0.020 Å, and the substituent benzene ring forms a dihedral angle of 85.89 (2)° with it. The Sn—Cl distances are in the range 2.4237 (3)–2.4454 (3) Å. There are N—H⋯Cl hydrogen bonds between SnCl(6) (2−) ions and rhodamine 6G cations as well as π–π stacking inter­actions between rhodamine 6G cations (inter­planar distance of 3.827 Å). International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915129/ /pubmed/21200545 http://dx.doi.org/10.1107/S1600536807066287 Text en © Venkatraman et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Venkatraman, Ramaiyer
Sitole, Lungile
Fronczek, Frank R.
Rhodamine 6G hexa­chlorido­stannate(IV) acetonitrile disolvate
title Rhodamine 6G hexa­chlorido­stannate(IV) acetonitrile disolvate
title_full Rhodamine 6G hexa­chlorido­stannate(IV) acetonitrile disolvate
title_fullStr Rhodamine 6G hexa­chlorido­stannate(IV) acetonitrile disolvate
title_full_unstemmed Rhodamine 6G hexa­chlorido­stannate(IV) acetonitrile disolvate
title_short Rhodamine 6G hexa­chlorido­stannate(IV) acetonitrile disolvate
title_sort rhodamine 6g hexa­chlorido­stannate(iv) acetonitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915129/
https://www.ncbi.nlm.nih.gov/pubmed/21200545
http://dx.doi.org/10.1107/S1600536807066287
work_keys_str_mv AT venkatramanramaiyer rhodamine6ghexachloridostannateivacetonitriledisolvate
AT sitolelungile rhodamine6ghexachloridostannateivacetonitriledisolvate
AT fronczekfrankr rhodamine6ghexachloridostannateivacetonitriledisolvate

Ejemplares similares