catena-Poly[[[diiodidocadmium(II)]-μ-1-(4-pyridylmeth­yl)-1H-benzimidazole] methanol hemisolvate]

In the title coordination polymer, {[CdI(2)(C(13)H(11)N(3))]·0.5CH(4)O}(n), each Cd(II) center is four-coordinated by two N-atom donors from two 1-(4-pyridylmeth­yl)-1H-benzimidazole (L) ligands and two iodide anions, forming a tetra­hedral coordination geometry. L ligands bridge adjacent Cd(II) ion...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Jun-Jie, Yan, Li-Fan, Hu, Tong-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915130/
https://www.ncbi.nlm.nih.gov/pubmed/21200548
http://dx.doi.org/10.1107/S1600536807061302
Descripción
Sumario:In the title coordination polymer, {[CdI(2)(C(13)H(11)N(3))]·0.5CH(4)O}(n), each Cd(II) center is four-coordinated by two N-atom donors from two 1-(4-pyridylmeth­yl)-1H-benzimidazole (L) ligands and two iodide anions, forming a tetra­hedral coordination geometry. L ligands bridge adjacent Cd(II) ions, generating two crystallographically independent approximately orthogonal one-dimensional chains. The methanol solvent mol­ecule associates with one of the chains via O—H⋯I inter­actions.

Ejemplares similares