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Tetrakis[μ-3-(3-pyridyl)acrylato-κ(2) O:O′]bis{(1,10-phenanthroline-κ(2) N,N′)[3-(3-pyridyl)acrylato-κ(2) O,O′]europium(III)} pentahydrate

The europium(III) ion in the title compound, [Eu(2)(C(8)H(6)NO(2))(6)(C(12)H(8)N(2))(2)]·5H(2)O, is coordinated by seven carboxyl­ate O atoms and two N atoms from one phenanthroline mol­ecule. The carboxyl­ate groups of 3-(3-pyrid­yl)acrylate link pairs of europium(III) ions, forming centrosymmetric...

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Detalles Bibliográficos
Autores principales: Liu, Chong-Bo, Wen, Hui-Liang, Deng, Fang, Zuo, Jun-Hui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915131/
https://www.ncbi.nlm.nih.gov/pubmed/21200549
http://dx.doi.org/10.1107/S1600536807066263
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author Liu, Chong-Bo
Wen, Hui-Liang
Deng, Fang
Zuo, Jun-Hui
author_facet Liu, Chong-Bo
Wen, Hui-Liang
Deng, Fang
Zuo, Jun-Hui
author_sort Liu, Chong-Bo
collection PubMed
description The europium(III) ion in the title compound, [Eu(2)(C(8)H(6)NO(2))(6)(C(12)H(8)N(2))(2)]·5H(2)O, is coordinated by seven carboxyl­ate O atoms and two N atoms from one phenanthroline mol­ecule. The carboxyl­ate groups of 3-(3-pyrid­yl)acrylate link pairs of europium(III) ions, forming centrosymmetric dinuclear units, which further assemble into a sheet parallel to the (001) plane through hydrogen-bonding inter­actions involving the uncoordinated water mol­ecules. One water molecule is disordered.
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spelling pubmed-29151312010-12-30 Tetrakis[μ-3-(3-pyridyl)acrylato-κ(2) O:O′]bis{(1,10-phenanthroline-κ(2) N,N′)[3-(3-pyridyl)acrylato-κ(2) O,O′]europium(III)} pentahydrate Liu, Chong-Bo Wen, Hui-Liang Deng, Fang Zuo, Jun-Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The europium(III) ion in the title compound, [Eu(2)(C(8)H(6)NO(2))(6)(C(12)H(8)N(2))(2)]·5H(2)O, is coordinated by seven carboxyl­ate O atoms and two N atoms from one phenanthroline mol­ecule. The carboxyl­ate groups of 3-(3-pyrid­yl)acrylate link pairs of europium(III) ions, forming centrosymmetric dinuclear units, which further assemble into a sheet parallel to the (001) plane through hydrogen-bonding inter­actions involving the uncoordinated water mol­ecules. One water molecule is disordered. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915131/ /pubmed/21200549 http://dx.doi.org/10.1107/S1600536807066263 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Liu, Chong-Bo
Wen, Hui-Liang
Deng, Fang
Zuo, Jun-Hui
Tetrakis[μ-3-(3-pyridyl)acrylato-κ(2) O:O′]bis{(1,10-phenanthroline-κ(2) N,N′)[3-(3-pyridyl)acrylato-κ(2) O,O′]europium(III)} pentahydrate
title Tetrakis[μ-3-(3-pyridyl)acrylato-κ(2) O:O′]bis{(1,10-phenanthroline-κ(2) N,N′)[3-(3-pyridyl)acrylato-κ(2) O,O′]europium(III)} pentahydrate
title_full Tetrakis[μ-3-(3-pyridyl)acrylato-κ(2) O:O′]bis{(1,10-phenanthroline-κ(2) N,N′)[3-(3-pyridyl)acrylato-κ(2) O,O′]europium(III)} pentahydrate
title_fullStr Tetrakis[μ-3-(3-pyridyl)acrylato-κ(2) O:O′]bis{(1,10-phenanthroline-κ(2) N,N′)[3-(3-pyridyl)acrylato-κ(2) O,O′]europium(III)} pentahydrate
title_full_unstemmed Tetrakis[μ-3-(3-pyridyl)acrylato-κ(2) O:O′]bis{(1,10-phenanthroline-κ(2) N,N′)[3-(3-pyridyl)acrylato-κ(2) O,O′]europium(III)} pentahydrate
title_short Tetrakis[μ-3-(3-pyridyl)acrylato-κ(2) O:O′]bis{(1,10-phenanthroline-κ(2) N,N′)[3-(3-pyridyl)acrylato-κ(2) O,O′]europium(III)} pentahydrate
title_sort tetrakis[μ-3-(3-pyridyl)acrylato-κ(2) o:o′]bis{(1,10-phenanthroline-κ(2) n,n′)[3-(3-pyridyl)acrylato-κ(2) o,o′]europium(iii)} pentahydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915131/
https://www.ncbi.nlm.nih.gov/pubmed/21200549
http://dx.doi.org/10.1107/S1600536807066263
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