[(1-Azulen­yl)methane­thiol­ato-κS](1,4,8,12-tetra­azacyclo­penta­decane-κ(4) N)zinc(II) perchlorate

In the title compound, [Zn(C(11)H(26)N(4))(C(11)H(9)S)]ClO(4), the Zn(II) atom is five-coordinated by four N atoms from a neutral 1,4,8,12-tetra­azacyclo­penta­decane aza-macrocycle mol­ecule, and one S atom from an azulenylmethane­thiol­ate ligand. Only monomers are found in the crystal. The coordi...

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Detalles Bibliográficos
Autores principales: Görls, Helmar, Notni, Johannes, Anders, Ernst
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915133/
https://www.ncbi.nlm.nih.gov/pubmed/21200551
http://dx.doi.org/10.1107/S1600536807047514
Descripción
Sumario:In the title compound, [Zn(C(11)H(26)N(4))(C(11)H(9)S)]ClO(4), the Zn(II) atom is five-coordinated by four N atoms from a neutral 1,4,8,12-tetra­azacyclo­penta­decane aza-macrocycle mol­ecule, and one S atom from an azulenylmethane­thiol­ate ligand. Only monomers are found in the crystal. The coordination geometry can be described as trigonal bipyramidal, with the thiol­ate group in an equatorial position. The Zn—N and Zn—S distances are in the usual ranges for this type of complex.

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