[(1-Azulen­yl)methane­thiol­ato-κS](1,4,8,12-tetra­azacyclo­penta­decane-κ(4) N)zinc(II) perchlorate

In the title compound, [Zn(C(11)H(26)N(4))(C(11)H(9)S)]ClO(4), the Zn(II) atom is five-coordinated by four N atoms from a neutral 1,4,8,12-tetra­azacyclo­penta­decane aza-macrocycle mol­ecule, and one S atom from an azulenylmethane­thiol­ate ligand. Only monomers are found in the crystal. The coordi...

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Detalles Bibliográficos
Autores principales: Görls, Helmar, Notni, Johannes, Anders, Ernst
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915133/
https://www.ncbi.nlm.nih.gov/pubmed/21200551
http://dx.doi.org/10.1107/S1600536807047514
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author Görls, Helmar
Notni, Johannes
Anders, Ernst
author_facet Görls, Helmar
Notni, Johannes
Anders, Ernst
author_sort Görls, Helmar
collection PubMed
description In the title compound, [Zn(C(11)H(26)N(4))(C(11)H(9)S)]ClO(4), the Zn(II) atom is five-coordinated by four N atoms from a neutral 1,4,8,12-tetra­azacyclo­penta­decane aza-macrocycle mol­ecule, and one S atom from an azulenylmethane­thiol­ate ligand. Only monomers are found in the crystal. The coordination geometry can be described as trigonal bipyramidal, with the thiol­ate group in an equatorial position. The Zn—N and Zn—S distances are in the usual ranges for this type of complex.
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spelling pubmed-29151332010-12-30 [(1-Azulen­yl)methane­thiol­ato-κS](1,4,8,12-tetra­azacyclo­penta­decane-κ(4) N)zinc(II) perchlorate Görls, Helmar Notni, Johannes Anders, Ernst Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(11)H(26)N(4))(C(11)H(9)S)]ClO(4), the Zn(II) atom is five-coordinated by four N atoms from a neutral 1,4,8,12-tetra­azacyclo­penta­decane aza-macrocycle mol­ecule, and one S atom from an azulenylmethane­thiol­ate ligand. Only monomers are found in the crystal. The coordination geometry can be described as trigonal bipyramidal, with the thiol­ate group in an equatorial position. The Zn—N and Zn—S distances are in the usual ranges for this type of complex. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915133/ /pubmed/21200551 http://dx.doi.org/10.1107/S1600536807047514 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Görls, Helmar
Notni, Johannes
Anders, Ernst
[(1-Azulen­yl)methane­thiol­ato-κS](1,4,8,12-tetra­azacyclo­penta­decane-κ(4) N)zinc(II) perchlorate
title [(1-Azulen­yl)methane­thiol­ato-κS](1,4,8,12-tetra­azacyclo­penta­decane-κ(4) N)zinc(II) perchlorate
title_full [(1-Azulen­yl)methane­thiol­ato-κS](1,4,8,12-tetra­azacyclo­penta­decane-κ(4) N)zinc(II) perchlorate
title_fullStr [(1-Azulen­yl)methane­thiol­ato-κS](1,4,8,12-tetra­azacyclo­penta­decane-κ(4) N)zinc(II) perchlorate
title_full_unstemmed [(1-Azulen­yl)methane­thiol­ato-κS](1,4,8,12-tetra­azacyclo­penta­decane-κ(4) N)zinc(II) perchlorate
title_short [(1-Azulen­yl)methane­thiol­ato-κS](1,4,8,12-tetra­azacyclo­penta­decane-κ(4) N)zinc(II) perchlorate
title_sort [(1-azulen­yl)methane­thiol­ato-κs](1,4,8,12-tetra­azacyclo­penta­decane-κ(4) n)zinc(ii) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915133/
https://www.ncbi.nlm.nih.gov/pubmed/21200551
http://dx.doi.org/10.1107/S1600536807047514
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AT notnijohannes 1azulenylmethanethiolatoks14812tetraazacyclopentadecanek4nzinciiperchlorate
AT andersernst 1azulenylmethanethiolatoks14812tetraazacyclopentadecanek4nzinciiperchlorate

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