[4′-(2-Bromo-5-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]bis(triphenyl­phosphine-κP)­copper(I) tetra­fluorido­borate dichloro­methane hemisolvate

In the title complex, [Cu(C(20)H(13)BrN(4))(C(18)H(15)P)(2)]BF(4)·0.5CH(2)Cl(2), the copper(I) cation adopts a distorted tetra­hedral arrangement, coordinated by two triphenyl­phosphine ligands and two N atoms of the potentially tridentate terpyridine ligand. One half-mol­ecule of dichloro­methane c...

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Detalles Bibliográficos
Autores principales: Polson, Matthew I. J., Hanan, Garry S., Taylor, Nicholas J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915135/
https://www.ncbi.nlm.nih.gov/pubmed/21200553
http://dx.doi.org/10.1107/S1600536807066238
Descripción
Sumario:In the title complex, [Cu(C(20)H(13)BrN(4))(C(18)H(15)P)(2)]BF(4)·0.5CH(2)Cl(2), the copper(I) cation adopts a distorted tetra­hedral arrangement, coordinated by two triphenyl­phosphine ligands and two N atoms of the potentially tridentate terpyridine ligand. One half-mol­ecule of dichloro­methane crystallizes with the complex. The chlorine atoms are disordered over two sites with occupancies fixed at 0.30 and 0.20 respectively. The N donor atom of the central pyridine inter­acts weakly with the copper centre at a distance of 3.071 Å.

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