[4′-(2-Bromo-5-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]bis(triphenyl­phosphine-κP)­copper(I) tetra­fluorido­borate dichloro­methane hemisolvate

In the title complex, [Cu(C(20)H(13)BrN(4))(C(18)H(15)P)(2)]BF(4)·0.5CH(2)Cl(2), the copper(I) cation adopts a distorted tetra­hedral arrangement, coordinated by two triphenyl­phosphine ligands and two N atoms of the potentially tridentate terpyridine ligand. One half-mol­ecule of dichloro­methane c...

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Detalles Bibliográficos
Autores principales: Polson, Matthew I. J., Hanan, Garry S., Taylor, Nicholas J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915135/
https://www.ncbi.nlm.nih.gov/pubmed/21200553
http://dx.doi.org/10.1107/S1600536807066238
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author Polson, Matthew I. J.
Hanan, Garry S.
Taylor, Nicholas J.
author_facet Polson, Matthew I. J.
Hanan, Garry S.
Taylor, Nicholas J.
author_sort Polson, Matthew I. J.
collection PubMed
description In the title complex, [Cu(C(20)H(13)BrN(4))(C(18)H(15)P)(2)]BF(4)·0.5CH(2)Cl(2), the copper(I) cation adopts a distorted tetra­hedral arrangement, coordinated by two triphenyl­phosphine ligands and two N atoms of the potentially tridentate terpyridine ligand. One half-mol­ecule of dichloro­methane crystallizes with the complex. The chlorine atoms are disordered over two sites with occupancies fixed at 0.30 and 0.20 respectively. The N donor atom of the central pyridine inter­acts weakly with the copper centre at a distance of 3.071 Å.
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spelling pubmed-29151352010-12-30 [4′-(2-Bromo-5-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]bis(triphenyl­phosphine-κP)­copper(I) tetra­fluorido­borate dichloro­methane hemisolvate Polson, Matthew I. J. Hanan, Garry S. Taylor, Nicholas J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(20)H(13)BrN(4))(C(18)H(15)P)(2)]BF(4)·0.5CH(2)Cl(2), the copper(I) cation adopts a distorted tetra­hedral arrangement, coordinated by two triphenyl­phosphine ligands and two N atoms of the potentially tridentate terpyridine ligand. One half-mol­ecule of dichloro­methane crystallizes with the complex. The chlorine atoms are disordered over two sites with occupancies fixed at 0.30 and 0.20 respectively. The N donor atom of the central pyridine inter­acts weakly with the copper centre at a distance of 3.071 Å. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915135/ /pubmed/21200553 http://dx.doi.org/10.1107/S1600536807066238 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Polson, Matthew I. J.
Hanan, Garry S.
Taylor, Nicholas J.
[4′-(2-Bromo-5-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]bis(triphenyl­phosphine-κP)­copper(I) tetra­fluorido­borate dichloro­methane hemisolvate
title [4′-(2-Bromo-5-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]bis(triphenyl­phosphine-κP)­copper(I) tetra­fluorido­borate dichloro­methane hemisolvate
title_full [4′-(2-Bromo-5-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]bis(triphenyl­phosphine-κP)­copper(I) tetra­fluorido­borate dichloro­methane hemisolvate
title_fullStr [4′-(2-Bromo-5-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]bis(triphenyl­phosphine-κP)­copper(I) tetra­fluorido­borate dichloro­methane hemisolvate
title_full_unstemmed [4′-(2-Bromo-5-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]bis(triphenyl­phosphine-κP)­copper(I) tetra­fluorido­borate dichloro­methane hemisolvate
title_short [4′-(2-Bromo-5-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]bis(triphenyl­phosphine-κP)­copper(I) tetra­fluorido­borate dichloro­methane hemisolvate
title_sort [4′-(2-bromo-5-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′]bis(triphenyl­phosphine-κp)­copper(i) tetra­fluorido­borate dichloro­methane hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915135/
https://www.ncbi.nlm.nih.gov/pubmed/21200553
http://dx.doi.org/10.1107/S1600536807066238
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AT taylornicholasj 42bromo5pyridyl2262terpyridinek3nnnbistriphenylphosphinekpcopperitetrafluoridoboratedichloromethanehemisolvate

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