Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tol­yl)methanone]palladium(II)

In the title compound, [PdCl(2)(C(5)H(8)N(2))(C(12)H(12)N(2)O)], the Pd atom adopts a slightly distorted trans-PdCl(2)N(2) square-planar arrangement. The different Pd—N bond lengths can be related to the the electron-withdrawing effect of the o-toluoyl group on the substituted pyrazole ligand. The c...

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Detalles Bibliográficos
Autores principales: Nelana, Simphiwe M., Kruger, Gert J., Darkwa, James
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915136/
https://www.ncbi.nlm.nih.gov/pubmed/21200554
http://dx.doi.org/10.1107/S1600536807066627
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author Nelana, Simphiwe M.
Kruger, Gert J.
Darkwa, James
author_facet Nelana, Simphiwe M.
Kruger, Gert J.
Darkwa, James
author_sort Nelana, Simphiwe M.
collection PubMed
description In the title compound, [PdCl(2)(C(5)H(8)N(2))(C(12)H(12)N(2)O)], the Pd atom adopts a slightly distorted trans-PdCl(2)N(2) square-planar arrangement. The different Pd—N bond lengths can be related to the the electron-withdrawing effect of the o-toluoyl group on the substituted pyrazole ligand. The complex crystallizes as centrosymmetric hydrogen-bonded dimers through N—H⋯Cl linkages.
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spelling pubmed-29151362010-12-30 Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tol­yl)methanone]palladium(II) Nelana, Simphiwe M. Kruger, Gert J. Darkwa, James Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdCl(2)(C(5)H(8)N(2))(C(12)H(12)N(2)O)], the Pd atom adopts a slightly distorted trans-PdCl(2)N(2) square-planar arrangement. The different Pd—N bond lengths can be related to the the electron-withdrawing effect of the o-toluoyl group on the substituted pyrazole ligand. The complex crystallizes as centrosymmetric hydrogen-bonded dimers through N—H⋯Cl linkages. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915136/ /pubmed/21200554 http://dx.doi.org/10.1107/S1600536807066627 Text en © Nelana et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nelana, Simphiwe M.
Kruger, Gert J.
Darkwa, James
Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tol­yl)methanone]palladium(II)
title Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tol­yl)methanone]palladium(II)
title_full Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tol­yl)methanone]palladium(II)
title_fullStr Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tol­yl)methanone]palladium(II)
title_full_unstemmed Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tol­yl)methanone]palladium(II)
title_short Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tol­yl)methanone]palladium(II)
title_sort dichlorido(3,5-dimethyl-1h-pyrazole)[(3,5-dimethyl-1h-pyrazol-1-yl)(o-tol­yl)methanone]palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915136/
https://www.ncbi.nlm.nih.gov/pubmed/21200554
http://dx.doi.org/10.1107/S1600536807066627
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AT krugergertj dichlorido35dimethyl1hpyrazole35dimethyl1hpyrazol1ylotolylmethanonepalladiumii
AT darkwajames dichlorido35dimethyl1hpyrazole35dimethyl1hpyrazol1ylotolylmethanonepalladiumii

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