Benzyl 5-ferrocenyl-3-(4-methyl­phen­yl)-2-pyrazoline-1-dithio­carboxyl­ate

In the title compound, [Fe(C(5)H(5))(C(23)H(21)N(2)S(2))], the cyclo­penta­dienyl rings of the ferrocenyl unit deviate slightly from the eclipsed form. In the pyrazoline ring, the N atom bonded to S-benzyl dithio­carbazate exhibits unconventional sp (2)-hybrid character in order to form an extended...

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Detalles Bibliográficos
Autores principales: Liu, Xiao-Lan, Tong, Ben-Wan, Zhao, Yue, Ye, Jun, Liu, Yong-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915138/
https://www.ncbi.nlm.nih.gov/pubmed/21200556
http://dx.doi.org/10.1107/S1600536807066536
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author Liu, Xiao-Lan
Tong, Ben-Wan
Zhao, Yue
Ye, Jun
Liu, Yong-Hong
author_facet Liu, Xiao-Lan
Tong, Ben-Wan
Zhao, Yue
Ye, Jun
Liu, Yong-Hong
author_sort Liu, Xiao-Lan
collection PubMed
description In the title compound, [Fe(C(5)H(5))(C(23)H(21)N(2)S(2))], the cyclo­penta­dienyl rings of the ferrocenyl unit deviate slightly from the eclipsed form. In the pyrazoline ring, the N atom bonded to S-benzyl dithio­carbazate exhibits unconventional sp (2)-hybrid character in order to form an extended conjugated system. The pyrazoline ring displays an envelope conformation. The mol­ecules are linked into chains along the b axis via C—H⋯S inter­molecular hydrogen bonds.
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spelling pubmed-29151382010-12-30 Benzyl 5-ferrocenyl-3-(4-methyl­phen­yl)-2-pyrazoline-1-dithio­carboxyl­ate Liu, Xiao-Lan Tong, Ben-Wan Zhao, Yue Ye, Jun Liu, Yong-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(23)H(21)N(2)S(2))], the cyclo­penta­dienyl rings of the ferrocenyl unit deviate slightly from the eclipsed form. In the pyrazoline ring, the N atom bonded to S-benzyl dithio­carbazate exhibits unconventional sp (2)-hybrid character in order to form an extended conjugated system. The pyrazoline ring displays an envelope conformation. The mol­ecules are linked into chains along the b axis via C—H⋯S inter­molecular hydrogen bonds. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915138/ /pubmed/21200556 http://dx.doi.org/10.1107/S1600536807066536 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Liu, Xiao-Lan
Tong, Ben-Wan
Zhao, Yue
Ye, Jun
Liu, Yong-Hong
Benzyl 5-ferrocenyl-3-(4-methyl­phen­yl)-2-pyrazoline-1-dithio­carboxyl­ate
title Benzyl 5-ferrocenyl-3-(4-methyl­phen­yl)-2-pyrazoline-1-dithio­carboxyl­ate
title_full Benzyl 5-ferrocenyl-3-(4-methyl­phen­yl)-2-pyrazoline-1-dithio­carboxyl­ate
title_fullStr Benzyl 5-ferrocenyl-3-(4-methyl­phen­yl)-2-pyrazoline-1-dithio­carboxyl­ate
title_full_unstemmed Benzyl 5-ferrocenyl-3-(4-methyl­phen­yl)-2-pyrazoline-1-dithio­carboxyl­ate
title_short Benzyl 5-ferrocenyl-3-(4-methyl­phen­yl)-2-pyrazoline-1-dithio­carboxyl­ate
title_sort benzyl 5-ferrocenyl-3-(4-methyl­phen­yl)-2-pyrazoline-1-dithio­carboxyl­ate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915138/
https://www.ncbi.nlm.nih.gov/pubmed/21200556
http://dx.doi.org/10.1107/S1600536807066536
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AT zhaoyue benzyl5ferrocenyl34methylphenyl2pyrazoline1dithiocarboxylate
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