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cis-Dichlorido(3-chloro-2-methyl­imino­phenyl-κ(2) C (1),N)-trans-bis­(trimethyl­phosphine-κP)cobalt(III)

In the title compound, [CoCl(2)(C(8)H(7)ClN)(C(3)H(9)P)(2)], the Co atom displays an octa­hedral coordination, with two cis Cl atoms perpendicular to two trans trimethyl­phosphine ligands as well as trans to the bidentate 3-chloro-2-methyl­imino­phenyl ligand.

Detalles Bibliográficos
Autores principales: Chen, Yue, Zhou, Jin, Li, Xiaoyan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915139/
https://www.ncbi.nlm.nih.gov/pubmed/21200558
http://dx.doi.org/10.1107/S1600536807062654
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author Chen, Yue
Zhou, Jin
Li, Xiaoyan
author_facet Chen, Yue
Zhou, Jin
Li, Xiaoyan
author_sort Chen, Yue
collection PubMed
description In the title compound, [CoCl(2)(C(8)H(7)ClN)(C(3)H(9)P)(2)], the Co atom displays an octa­hedral coordination, with two cis Cl atoms perpendicular to two trans trimethyl­phosphine ligands as well as trans to the bidentate 3-chloro-2-methyl­imino­phenyl ligand.
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spelling pubmed-29151392010-12-30 cis-Dichlorido(3-chloro-2-methyl­imino­phenyl-κ(2) C (1),N)-trans-bis­(trimethyl­phosphine-κP)cobalt(III) Chen, Yue Zhou, Jin Li, Xiaoyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(2)(C(8)H(7)ClN)(C(3)H(9)P)(2)], the Co atom displays an octa­hedral coordination, with two cis Cl atoms perpendicular to two trans trimethyl­phosphine ligands as well as trans to the bidentate 3-chloro-2-methyl­imino­phenyl ligand. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915139/ /pubmed/21200558 http://dx.doi.org/10.1107/S1600536807062654 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Chen, Yue
Zhou, Jin
Li, Xiaoyan
cis-Dichlorido(3-chloro-2-methyl­imino­phenyl-κ(2) C (1),N)-trans-bis­(trimethyl­phosphine-κP)cobalt(III)
title cis-Dichlorido(3-chloro-2-methyl­imino­phenyl-κ(2) C (1),N)-trans-bis­(trimethyl­phosphine-κP)cobalt(III)
title_full cis-Dichlorido(3-chloro-2-methyl­imino­phenyl-κ(2) C (1),N)-trans-bis­(trimethyl­phosphine-κP)cobalt(III)
title_fullStr cis-Dichlorido(3-chloro-2-methyl­imino­phenyl-κ(2) C (1),N)-trans-bis­(trimethyl­phosphine-κP)cobalt(III)
title_full_unstemmed cis-Dichlorido(3-chloro-2-methyl­imino­phenyl-κ(2) C (1),N)-trans-bis­(trimethyl­phosphine-κP)cobalt(III)
title_short cis-Dichlorido(3-chloro-2-methyl­imino­phenyl-κ(2) C (1),N)-trans-bis­(trimethyl­phosphine-κP)cobalt(III)
title_sort cis-dichlorido(3-chloro-2-methyl­imino­phenyl-κ(2) c (1),n)-trans-bis­(trimethyl­phosphine-κp)cobalt(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915139/
https://www.ncbi.nlm.nih.gov/pubmed/21200558
http://dx.doi.org/10.1107/S1600536807062654
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