Bis[2-(2-hydroxy-3-meth­oxy­phen­yl)benzimidazolium] tetrachlorido­cuprate(II) methanol disolvate

In the title compound, (C(14)H(13)N(2)O(2))(2)[CuCl(4)]·2CH(4)O, the geometry of the CuC1(4) (2−) ions (Cu site symmetry 2) is inter­mediate between tetra­hedral and square-planar. The dihedral angle between the benzimidazole and benzene ring systems is 8.74(14)°. A network of N—H⋯O, N—H⋯Cl and O—H⋯...

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Detalles Bibliográficos
Autores principales: Xue, Ruiting, Niu, Meiju, Dou, Jianmin, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915140/
https://www.ncbi.nlm.nih.gov/pubmed/21200559
http://dx.doi.org/10.1107/S1600536807066214
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author Xue, Ruiting
Niu, Meiju
Dou, Jianmin
Wang, Daqi
author_facet Xue, Ruiting
Niu, Meiju
Dou, Jianmin
Wang, Daqi
author_sort Xue, Ruiting
collection PubMed
description In the title compound, (C(14)H(13)N(2)O(2))(2)[CuCl(4)]·2CH(4)O, the geometry of the CuC1(4) (2−) ions (Cu site symmetry 2) is inter­mediate between tetra­hedral and square-planar. The dihedral angle between the benzimidazole and benzene ring systems is 8.74(14)°. A network of N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds helps to consoldiate the structure. Aromatic π–π stacking inter­actions involving the benzimidazole ring system, with a centroid–centroid distance of 3.785 (3) Å, also occur.
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spelling pubmed-29151402010-12-30 Bis[2-(2-hydroxy-3-meth­oxy­phen­yl)benzimidazolium] tetrachlorido­cuprate(II) methanol disolvate Xue, Ruiting Niu, Meiju Dou, Jianmin Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(14)H(13)N(2)O(2))(2)[CuCl(4)]·2CH(4)O, the geometry of the CuC1(4) (2−) ions (Cu site symmetry 2) is inter­mediate between tetra­hedral and square-planar. The dihedral angle between the benzimidazole and benzene ring systems is 8.74(14)°. A network of N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds helps to consoldiate the structure. Aromatic π–π stacking inter­actions involving the benzimidazole ring system, with a centroid–centroid distance of 3.785 (3) Å, also occur. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915140/ /pubmed/21200559 http://dx.doi.org/10.1107/S1600536807066214 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Xue, Ruiting
Niu, Meiju
Dou, Jianmin
Wang, Daqi
Bis[2-(2-hydroxy-3-meth­oxy­phen­yl)benzimidazolium] tetrachlorido­cuprate(II) methanol disolvate
title Bis[2-(2-hydroxy-3-meth­oxy­phen­yl)benzimidazolium] tetrachlorido­cuprate(II) methanol disolvate
title_full Bis[2-(2-hydroxy-3-meth­oxy­phen­yl)benzimidazolium] tetrachlorido­cuprate(II) methanol disolvate
title_fullStr Bis[2-(2-hydroxy-3-meth­oxy­phen­yl)benzimidazolium] tetrachlorido­cuprate(II) methanol disolvate
title_full_unstemmed Bis[2-(2-hydroxy-3-meth­oxy­phen­yl)benzimidazolium] tetrachlorido­cuprate(II) methanol disolvate
title_short Bis[2-(2-hydroxy-3-meth­oxy­phen­yl)benzimidazolium] tetrachlorido­cuprate(II) methanol disolvate
title_sort bis[2-(2-hydroxy-3-meth­oxy­phen­yl)benzimidazolium] tetrachlorido­cuprate(ii) methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915140/
https://www.ncbi.nlm.nih.gov/pubmed/21200559
http://dx.doi.org/10.1107/S1600536807066214
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AT doujianmin bis22hydroxy3methoxyphenylbenzimidazoliumtetrachloridocuprateiimethanoldisolvate
AT wangdaqi bis22hydroxy3methoxyphenylbenzimidazoliumtetrachloridocuprateiimethanoldisolvate

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