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Tris[4-(2-pyridylmethyleneamino)phenol]iron(II) bis(perchlorate)
In the title compound, [Fe(C(12)H(10)N(2)O)(3)](ClO(4))(2), the metal center is coordinated by six N atoms from the three bidentate chelating ligands in a distorted octahedral coordination geometry, with overall formation of the meridional (OC-6-21) isomer. Intermolecular O—H⋯O hydrogen bonds betw...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915141/ https://www.ncbi.nlm.nih.gov/pubmed/21200560 http://dx.doi.org/10.1107/S1600536807066688 |
Sumario: | In the title compound, [Fe(C(12)H(10)N(2)O)(3)](ClO(4))(2), the metal center is coordinated by six N atoms from the three bidentate chelating ligands in a distorted octahedral coordination geometry, with overall formation of the meridional (OC-6-21) isomer. Intermolecular O—H⋯O hydrogen bonds between the hydroxyl groups of the cation and the counter-anions form an infinite one-dimensional chain in the c-axis direction. |
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