Octa­carbon­yl(5-meth­oxy-2,3-dihydro-1H-benzimidazol-2-yl)di-μ(3)-sulfido-diiron(I)iron(II)(2 Fe—Fe)

The title compound, [Fe(3)(C(8)H(8)N(2)O)S(2)(CO)(8)], was prepared by the direct reaction of Fe(3)(CO)(12) and 5-meth­oxy-1H-benzoimidazole-2-thiol in tetra­hydro­furan. Desulfurization took place readily to form a sulfide carbonyl cluster. The mol­ecule contains a triangle consisting of three Fe a...

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Detalles Bibliográficos
Autores principales: Zhang, Tingting, Wang, Mei, Li, Ping, Sun, Licheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915144/
https://www.ncbi.nlm.nih.gov/pubmed/21200564
http://dx.doi.org/10.1107/S160053680706415X
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author Zhang, Tingting
Wang, Mei
Li, Ping
Sun, Licheng
author_facet Zhang, Tingting
Wang, Mei
Li, Ping
Sun, Licheng
author_sort Zhang, Tingting
collection PubMed
description The title compound, [Fe(3)(C(8)H(8)N(2)O)S(2)(CO)(8)], was prepared by the direct reaction of Fe(3)(CO)(12) and 5-meth­oxy-1H-benzoimidazole-2-thiol in tetra­hydro­furan. Desulfurization took place readily to form a sulfide carbonyl cluster. The mol­ecule contains a triangle consisting of three Fe atoms capped by two S atoms above and below. There are two Fe—Fe bonds [2.6322 (5) and 2.5582 (5) Å] in the triangle; the length of the third edge [3.3987 (5) Å] is too long to represent an Fe—Fe bond.
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spelling pubmed-29151442010-12-30 Octa­carbon­yl(5-meth­oxy-2,3-dihydro-1H-benzimidazol-2-yl)di-μ(3)-sulfido-diiron(I)iron(II)(2 Fe—Fe) Zhang, Tingting Wang, Mei Li, Ping Sun, Licheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(3)(C(8)H(8)N(2)O)S(2)(CO)(8)], was prepared by the direct reaction of Fe(3)(CO)(12) and 5-meth­oxy-1H-benzoimidazole-2-thiol in tetra­hydro­furan. Desulfurization took place readily to form a sulfide carbonyl cluster. The mol­ecule contains a triangle consisting of three Fe atoms capped by two S atoms above and below. There are two Fe—Fe bonds [2.6322 (5) and 2.5582 (5) Å] in the triangle; the length of the third edge [3.3987 (5) Å] is too long to represent an Fe—Fe bond. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915144/ /pubmed/21200564 http://dx.doi.org/10.1107/S160053680706415X Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Zhang, Tingting
Wang, Mei
Li, Ping
Sun, Licheng
Octa­carbon­yl(5-meth­oxy-2,3-dihydro-1H-benzimidazol-2-yl)di-μ(3)-sulfido-diiron(I)iron(II)(2 Fe—Fe)
title Octa­carbon­yl(5-meth­oxy-2,3-dihydro-1H-benzimidazol-2-yl)di-μ(3)-sulfido-diiron(I)iron(II)(2 Fe—Fe)
title_full Octa­carbon­yl(5-meth­oxy-2,3-dihydro-1H-benzimidazol-2-yl)di-μ(3)-sulfido-diiron(I)iron(II)(2 Fe—Fe)
title_fullStr Octa­carbon­yl(5-meth­oxy-2,3-dihydro-1H-benzimidazol-2-yl)di-μ(3)-sulfido-diiron(I)iron(II)(2 Fe—Fe)
title_full_unstemmed Octa­carbon­yl(5-meth­oxy-2,3-dihydro-1H-benzimidazol-2-yl)di-μ(3)-sulfido-diiron(I)iron(II)(2 Fe—Fe)
title_short Octa­carbon­yl(5-meth­oxy-2,3-dihydro-1H-benzimidazol-2-yl)di-μ(3)-sulfido-diiron(I)iron(II)(2 Fe—Fe)
title_sort octa­carbon­yl(5-meth­oxy-2,3-dihydro-1h-benzimidazol-2-yl)di-μ(3)-sulfido-diiron(i)iron(ii)(2 fe—fe)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915144/
https://www.ncbi.nlm.nih.gov/pubmed/21200564
http://dx.doi.org/10.1107/S160053680706415X
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AT sunlicheng octacarbonyl5methoxy23dihydro1hbenzimidazol2yldim3sulfidodiironiironii2fefe

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