Di-μ-thio­cyanato-bis­({2,4-dichloro-6-[2-(diethyl­amino)ethyl­imino­meth­yl]phenolato}copper(II))

The title compound, [Cu(2)(NCS)(2)(C(13)H(17)Cl(2)N(2)O)(2)], was obtained by the reaction of 3,5-dichloro­salicylaldehyde, N,N-diethyl­ethane-1,2-diamine, sodium thio­cyanate, and copper(II) acetate in an ethanol solution. It crystallizes as a centrosymmetric dimer with a very long Cu⋯S axial bond...

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Detalles Bibliográficos
Autores principales: Li, Xian-Wen, Qiu, Yang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915145/
https://www.ncbi.nlm.nih.gov/pubmed/21200565
http://dx.doi.org/10.1107/S1600536807063325
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author Li, Xian-Wen
Qiu, Yang
author_facet Li, Xian-Wen
Qiu, Yang
author_sort Li, Xian-Wen
collection PubMed
description The title compound, [Cu(2)(NCS)(2)(C(13)H(17)Cl(2)N(2)O)(2)], was obtained by the reaction of 3,5-dichloro­salicylaldehyde, N,N-diethyl­ethane-1,2-diamine, sodium thio­cyanate, and copper(II) acetate in an ethanol solution. It crystallizes as a centrosymmetric dimer with a very long Cu⋯S axial bond [2.972 (3) Å]. The Cu atom is five-coordinated by the three donor atoms of the Schiff base ligand, 2,4-dichloro-6-[(2-diethyl­amino­ethyl­imino)meth­yl]phenol, one N atom of a thio­cyanate group, and one S atom of a symmetry-related thio­cyanate group, forming a slightly distorted square-pyramidal geometry.
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spelling pubmed-29151452010-12-30 Di-μ-thio­cyanato-bis­({2,4-dichloro-6-[2-(diethyl­amino)ethyl­imino­meth­yl]phenolato}copper(II)) Li, Xian-Wen Qiu, Yang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(NCS)(2)(C(13)H(17)Cl(2)N(2)O)(2)], was obtained by the reaction of 3,5-dichloro­salicylaldehyde, N,N-diethyl­ethane-1,2-diamine, sodium thio­cyanate, and copper(II) acetate in an ethanol solution. It crystallizes as a centrosymmetric dimer with a very long Cu⋯S axial bond [2.972 (3) Å]. The Cu atom is five-coordinated by the three donor atoms of the Schiff base ligand, 2,4-dichloro-6-[(2-diethyl­amino­ethyl­imino)meth­yl]phenol, one N atom of a thio­cyanate group, and one S atom of a symmetry-related thio­cyanate group, forming a slightly distorted square-pyramidal geometry. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915145/ /pubmed/21200565 http://dx.doi.org/10.1107/S1600536807063325 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Li, Xian-Wen
Qiu, Yang
Di-μ-thio­cyanato-bis­({2,4-dichloro-6-[2-(diethyl­amino)ethyl­imino­meth­yl]phenolato}copper(II))
title Di-μ-thio­cyanato-bis­({2,4-dichloro-6-[2-(diethyl­amino)ethyl­imino­meth­yl]phenolato}copper(II))
title_full Di-μ-thio­cyanato-bis­({2,4-dichloro-6-[2-(diethyl­amino)ethyl­imino­meth­yl]phenolato}copper(II))
title_fullStr Di-μ-thio­cyanato-bis­({2,4-dichloro-6-[2-(diethyl­amino)ethyl­imino­meth­yl]phenolato}copper(II))
title_full_unstemmed Di-μ-thio­cyanato-bis­({2,4-dichloro-6-[2-(diethyl­amino)ethyl­imino­meth­yl]phenolato}copper(II))
title_short Di-μ-thio­cyanato-bis­({2,4-dichloro-6-[2-(diethyl­amino)ethyl­imino­meth­yl]phenolato}copper(II))
title_sort di-μ-thio­cyanato-bis­({2,4-dichloro-6-[2-(diethyl­amino)ethyl­imino­meth­yl]phenolato}copper(ii))
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915145/
https://www.ncbi.nlm.nih.gov/pubmed/21200565
http://dx.doi.org/10.1107/S1600536807063325
work_keys_str_mv AT lixianwen dimthiocyanatobis24dichloro62diethylaminoethyliminomethylphenolatocopperii
AT qiuyang dimthiocyanatobis24dichloro62diethylaminoethyliminomethylphenolatocopperii

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