Bis(2-benzoyl-1-phenyl­ethenolato-κ(2) O,O′)(ethanol-κO)dioxidouranium(VI)

In the title compound, [U(C(15)H(11)O(2))(2)O(2)(C(2)H(6)O)], the U(VI )atom has a penta­gonal–bipyramidal coordination geometry. The two so-called ‘-yl’ O atoms occupy the axial positions whereas four O atoms from the two chelating dibenzoyl­methanate ligands and the O atom from the ethanol mol­ecu...

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Detalles Bibliográficos
Autores principales: Takao, Koichiro, Ikeda, Yasuhisa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915146/
https://www.ncbi.nlm.nih.gov/pubmed/21200566
http://dx.doi.org/10.1107/S1600536807063799
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author Takao, Koichiro
Ikeda, Yasuhisa
author_facet Takao, Koichiro
Ikeda, Yasuhisa
author_sort Takao, Koichiro
collection PubMed
description In the title compound, [U(C(15)H(11)O(2))(2)O(2)(C(2)H(6)O)], the U(VI )atom has a penta­gonal–bipyramidal coordination geometry. The two so-called ‘-yl’ O atoms occupy the axial positions whereas four O atoms from the two chelating dibenzoyl­methanate ligands and the O atom from the ethanol mol­ecule are situated in the equatorial plane. Inter­molecular hydrogen bonds between one of the ‘-yl’ O atoms and the ethanol OH group assemble mol­ecules into a centrosymmetric dimer.
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spelling pubmed-29151462010-12-30 Bis(2-benzoyl-1-phenyl­ethenolato-κ(2) O,O′)(ethanol-κO)dioxidouranium(VI) Takao, Koichiro Ikeda, Yasuhisa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [U(C(15)H(11)O(2))(2)O(2)(C(2)H(6)O)], the U(VI )atom has a penta­gonal–bipyramidal coordination geometry. The two so-called ‘-yl’ O atoms occupy the axial positions whereas four O atoms from the two chelating dibenzoyl­methanate ligands and the O atom from the ethanol mol­ecule are situated in the equatorial plane. Inter­molecular hydrogen bonds between one of the ‘-yl’ O atoms and the ethanol OH group assemble mol­ecules into a centrosymmetric dimer. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915146/ /pubmed/21200566 http://dx.doi.org/10.1107/S1600536807063799 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Takao, Koichiro
Ikeda, Yasuhisa
Bis(2-benzoyl-1-phenyl­ethenolato-κ(2) O,O′)(ethanol-κO)dioxidouranium(VI)
title Bis(2-benzoyl-1-phenyl­ethenolato-κ(2) O,O′)(ethanol-κO)dioxidouranium(VI)
title_full Bis(2-benzoyl-1-phenyl­ethenolato-κ(2) O,O′)(ethanol-κO)dioxidouranium(VI)
title_fullStr Bis(2-benzoyl-1-phenyl­ethenolato-κ(2) O,O′)(ethanol-κO)dioxidouranium(VI)
title_full_unstemmed Bis(2-benzoyl-1-phenyl­ethenolato-κ(2) O,O′)(ethanol-κO)dioxidouranium(VI)
title_short Bis(2-benzoyl-1-phenyl­ethenolato-κ(2) O,O′)(ethanol-κO)dioxidouranium(VI)
title_sort bis(2-benzoyl-1-phenyl­ethenolato-κ(2) o,o′)(ethanol-κo)dioxidouranium(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915146/
https://www.ncbi.nlm.nih.gov/pubmed/21200566
http://dx.doi.org/10.1107/S1600536807063799
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