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Tris(ethyl carbazate-κ(2) N,O)nickel(II) dinitrate

The asymmetric unit of the title compound, [Ni(C(3)H(8)N(2)O(2))(3)](NO(3))(2), contains two independent cations, each built up around a fac-NiN(3)O(3) octa­hedron, and four nitrate anions. Numerous cation-to-anion N—H⋯O hydrogen bonds, some of which are bifurcated, help to establish the packing....

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Detalles Bibliográficos
Autores principales: Srinivasan, Krishnan, Govindarajan, Subbaiah, Harrison, William T. A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915148/
https://www.ncbi.nlm.nih.gov/pubmed/21200569
http://dx.doi.org/10.1107/S1600536807059053
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author Srinivasan, Krishnan
Govindarajan, Subbaiah
Harrison, William T. A.
author_facet Srinivasan, Krishnan
Govindarajan, Subbaiah
Harrison, William T. A.
author_sort Srinivasan, Krishnan
collection PubMed
description The asymmetric unit of the title compound, [Ni(C(3)H(8)N(2)O(2))(3)](NO(3))(2), contains two independent cations, each built up around a fac-NiN(3)O(3) octa­hedron, and four nitrate anions. Numerous cation-to-anion N—H⋯O hydrogen bonds, some of which are bifurcated, help to establish the packing.
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spelling pubmed-29151482010-12-30 Tris(ethyl carbazate-κ(2) N,O)nickel(II) dinitrate Srinivasan, Krishnan Govindarajan, Subbaiah Harrison, William T. A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ni(C(3)H(8)N(2)O(2))(3)](NO(3))(2), contains two independent cations, each built up around a fac-NiN(3)O(3) octa­hedron, and four nitrate anions. Numerous cation-to-anion N—H⋯O hydrogen bonds, some of which are bifurcated, help to establish the packing. International Union of Crystallography 2007-12-18 /pmc/articles/PMC2915148/ /pubmed/21200569 http://dx.doi.org/10.1107/S1600536807059053 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Srinivasan, Krishnan
Govindarajan, Subbaiah
Harrison, William T. A.
Tris(ethyl carbazate-κ(2) N,O)nickel(II) dinitrate
title Tris(ethyl carbazate-κ(2) N,O)nickel(II) dinitrate
title_full Tris(ethyl carbazate-κ(2) N,O)nickel(II) dinitrate
title_fullStr Tris(ethyl carbazate-κ(2) N,O)nickel(II) dinitrate
title_full_unstemmed Tris(ethyl carbazate-κ(2) N,O)nickel(II) dinitrate
title_short Tris(ethyl carbazate-κ(2) N,O)nickel(II) dinitrate
title_sort tris(ethyl carbazate-κ(2) n,o)nickel(ii) dinitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915148/
https://www.ncbi.nlm.nih.gov/pubmed/21200569
http://dx.doi.org/10.1107/S1600536807059053
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