catena-Poly[cobalt(II)-bis­(μ-3,7-dichloro­quinoline-8-carboxyl­ato-κ(3) N,O:O′)]

In the crystal structure of the title compound, [Co(C(10)H(4)Cl(2)NO(2))(2)](n), the Co(II) cation lies on a twofold rotation axis. Each cation is N,O-chelated by the carboxyl­ate anions of two 3,7-dichloro­quinoline-8-carboxyl­ate ligands. The second carboxyl­ate O atom of each ligand coordinates t...

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Detalles Bibliográficos
Autores principales: Li, Zequan, Wu, Fengjing, Gong, Yun, Zhang, Yunhuai, Bai, Chenguang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915151/
https://www.ncbi.nlm.nih.gov/pubmed/21200573
http://dx.doi.org/10.1107/S1600536807066755
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author Li, Zequan
Wu, Fengjing
Gong, Yun
Zhang, Yunhuai
Bai, Chenguang
author_facet Li, Zequan
Wu, Fengjing
Gong, Yun
Zhang, Yunhuai
Bai, Chenguang
author_sort Li, Zequan
collection PubMed
description In the crystal structure of the title compound, [Co(C(10)H(4)Cl(2)NO(2))(2)](n), the Co(II) cation lies on a twofold rotation axis. Each cation is N,O-chelated by the carboxyl­ate anions of two 3,7-dichloro­quinoline-8-carboxyl­ate ligands. The second carboxyl­ate O atom of each ligand coordinates to the Co(II) cation of an adjacent mol­ecule, linking the cations into a linear chain. Strong inter­chain π–π stacking inter­actions are observed in the crystal structure (perpendicular distance 3.42 Å, centroid-to-centroid distance 3.874 Å)
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spelling pubmed-29151512010-12-30 catena-Poly[cobalt(II)-bis­(μ-3,7-dichloro­quinoline-8-carboxyl­ato-κ(3) N,O:O′)] Li, Zequan Wu, Fengjing Gong, Yun Zhang, Yunhuai Bai, Chenguang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Co(C(10)H(4)Cl(2)NO(2))(2)](n), the Co(II) cation lies on a twofold rotation axis. Each cation is N,O-chelated by the carboxyl­ate anions of two 3,7-dichloro­quinoline-8-carboxyl­ate ligands. The second carboxyl­ate O atom of each ligand coordinates to the Co(II) cation of an adjacent mol­ecule, linking the cations into a linear chain. Strong inter­chain π–π stacking inter­actions are observed in the crystal structure (perpendicular distance 3.42 Å, centroid-to-centroid distance 3.874 Å) International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915151/ /pubmed/21200573 http://dx.doi.org/10.1107/S1600536807066755 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Zequan
Wu, Fengjing
Gong, Yun
Zhang, Yunhuai
Bai, Chenguang
catena-Poly[cobalt(II)-bis­(μ-3,7-dichloro­quinoline-8-carboxyl­ato-κ(3) N,O:O′)]
title catena-Poly[cobalt(II)-bis­(μ-3,7-dichloro­quinoline-8-carboxyl­ato-κ(3) N,O:O′)]
title_full catena-Poly[cobalt(II)-bis­(μ-3,7-dichloro­quinoline-8-carboxyl­ato-κ(3) N,O:O′)]
title_fullStr catena-Poly[cobalt(II)-bis­(μ-3,7-dichloro­quinoline-8-carboxyl­ato-κ(3) N,O:O′)]
title_full_unstemmed catena-Poly[cobalt(II)-bis­(μ-3,7-dichloro­quinoline-8-carboxyl­ato-κ(3) N,O:O′)]
title_short catena-Poly[cobalt(II)-bis­(μ-3,7-dichloro­quinoline-8-carboxyl­ato-κ(3) N,O:O′)]
title_sort catena-poly[cobalt(ii)-bis­(μ-3,7-dichloro­quinoline-8-carboxyl­ato-κ(3) n,o:o′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915151/
https://www.ncbi.nlm.nih.gov/pubmed/21200573
http://dx.doi.org/10.1107/S1600536807066755
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