(1,10-Phenanthroline-κ(2) N,N′)bis­(2,2,6,6-tetra­methyl­heptane-3,5-dionato-κ(2) O,O′)nickel(II)

The title compound, [Ni(C(11)H(19)O(2))(2)(C(12)H(8)N(2))], was obtained from the reaction of bis­(2,2,6,6-tetra­methyl­heptane-3,5-dionato)nickel(II), [Ni(dpm)], and 1,10-phenanthroline (phen). The Ni(II) ion is coordinated by four O atoms from two dpm ligands and two N atoms from a phen ligand in...

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Detalles Bibliográficos
Autores principales: Kaitner, Branko, Mesarek, Krešo, Meštrović, Ernest
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915153/
https://www.ncbi.nlm.nih.gov/pubmed/21200575
http://dx.doi.org/10.1107/S160053680706672X
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author Kaitner, Branko
Mesarek, Krešo
Meštrović, Ernest
author_facet Kaitner, Branko
Mesarek, Krešo
Meštrović, Ernest
author_sort Kaitner, Branko
collection PubMed
description The title compound, [Ni(C(11)H(19)O(2))(2)(C(12)H(8)N(2))], was obtained from the reaction of bis­(2,2,6,6-tetra­methyl­heptane-3,5-dionato)nickel(II), [Ni(dpm)], and 1,10-phenanthroline (phen). The Ni(II) ion is coordinated by four O atoms from two dpm ligands and two N atoms from a phen ligand in a slightly distorted octa­hedral environment. The methyl C atoms of two of the tert-butyl groups are disordered over two sites, having approximate occupancies of 0.85 and 0.15 for the two components. In the crystal structure, there are no direction-specific inter­actions. Thermal studies showed that the title complex is stable to 623 K.
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spelling pubmed-29151532010-12-30 (1,10-Phenanthroline-κ(2) N,N′)bis­(2,2,6,6-tetra­methyl­heptane-3,5-dionato-κ(2) O,O′)nickel(II) Kaitner, Branko Mesarek, Krešo Meštrović, Ernest Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(11)H(19)O(2))(2)(C(12)H(8)N(2))], was obtained from the reaction of bis­(2,2,6,6-tetra­methyl­heptane-3,5-dionato)nickel(II), [Ni(dpm)], and 1,10-phenanthroline (phen). The Ni(II) ion is coordinated by four O atoms from two dpm ligands and two N atoms from a phen ligand in a slightly distorted octa­hedral environment. The methyl C atoms of two of the tert-butyl groups are disordered over two sites, having approximate occupancies of 0.85 and 0.15 for the two components. In the crystal structure, there are no direction-specific inter­actions. Thermal studies showed that the title complex is stable to 623 K. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915153/ /pubmed/21200575 http://dx.doi.org/10.1107/S160053680706672X Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Kaitner, Branko
Mesarek, Krešo
Meštrović, Ernest
(1,10-Phenanthroline-κ(2) N,N′)bis­(2,2,6,6-tetra­methyl­heptane-3,5-dionato-κ(2) O,O′)nickel(II)
title (1,10-Phenanthroline-κ(2) N,N′)bis­(2,2,6,6-tetra­methyl­heptane-3,5-dionato-κ(2) O,O′)nickel(II)
title_full (1,10-Phenanthroline-κ(2) N,N′)bis­(2,2,6,6-tetra­methyl­heptane-3,5-dionato-κ(2) O,O′)nickel(II)
title_fullStr (1,10-Phenanthroline-κ(2) N,N′)bis­(2,2,6,6-tetra­methyl­heptane-3,5-dionato-κ(2) O,O′)nickel(II)
title_full_unstemmed (1,10-Phenanthroline-κ(2) N,N′)bis­(2,2,6,6-tetra­methyl­heptane-3,5-dionato-κ(2) O,O′)nickel(II)
title_short (1,10-Phenanthroline-κ(2) N,N′)bis­(2,2,6,6-tetra­methyl­heptane-3,5-dionato-κ(2) O,O′)nickel(II)
title_sort (1,10-phenanthroline-κ(2) n,n′)bis­(2,2,6,6-tetra­methyl­heptane-3,5-dionato-κ(2) o,o′)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915153/
https://www.ncbi.nlm.nih.gov/pubmed/21200575
http://dx.doi.org/10.1107/S160053680706672X
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AT mesarekkreso 110phenanthrolinek2nnbis2266tetramethylheptane35dionatok2oonickelii
AT mestrovicernest 110phenanthrolinek2nnbis2266tetramethylheptane35dionatok2oonickelii

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