Cargando…
(1,10-Phenanthroline-κ(2) N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ(2) O,O′)nickel(II)
The title compound, [Ni(C(11)H(19)O(2))(2)(C(12)H(8)N(2))], was obtained from the reaction of bis(2,2,6,6-tetramethylheptane-3,5-dionato)nickel(II), [Ni(dpm)], and 1,10-phenanthroline (phen). The Ni(II) ion is coordinated by four O atoms from two dpm ligands and two N atoms from a phen ligand in...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915153/ https://www.ncbi.nlm.nih.gov/pubmed/21200575 http://dx.doi.org/10.1107/S160053680706672X |
_version_ | 1782184872749563904 |
---|---|
author | Kaitner, Branko Mesarek, Krešo Meštrović, Ernest |
author_facet | Kaitner, Branko Mesarek, Krešo Meštrović, Ernest |
author_sort | Kaitner, Branko |
collection | PubMed |
description | The title compound, [Ni(C(11)H(19)O(2))(2)(C(12)H(8)N(2))], was obtained from the reaction of bis(2,2,6,6-tetramethylheptane-3,5-dionato)nickel(II), [Ni(dpm)], and 1,10-phenanthroline (phen). The Ni(II) ion is coordinated by four O atoms from two dpm ligands and two N atoms from a phen ligand in a slightly distorted octahedral environment. The methyl C atoms of two of the tert-butyl groups are disordered over two sites, having approximate occupancies of 0.85 and 0.15 for the two components. In the crystal structure, there are no direction-specific interactions. Thermal studies showed that the title complex is stable to 623 K. |
format | Text |
id | pubmed-2915153 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29151532010-12-30 (1,10-Phenanthroline-κ(2) N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ(2) O,O′)nickel(II) Kaitner, Branko Mesarek, Krešo Meštrović, Ernest Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(11)H(19)O(2))(2)(C(12)H(8)N(2))], was obtained from the reaction of bis(2,2,6,6-tetramethylheptane-3,5-dionato)nickel(II), [Ni(dpm)], and 1,10-phenanthroline (phen). The Ni(II) ion is coordinated by four O atoms from two dpm ligands and two N atoms from a phen ligand in a slightly distorted octahedral environment. The methyl C atoms of two of the tert-butyl groups are disordered over two sites, having approximate occupancies of 0.85 and 0.15 for the two components. In the crystal structure, there are no direction-specific interactions. Thermal studies showed that the title complex is stable to 623 K. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915153/ /pubmed/21200575 http://dx.doi.org/10.1107/S160053680706672X Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Kaitner, Branko Mesarek, Krešo Meštrović, Ernest (1,10-Phenanthroline-κ(2) N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ(2) O,O′)nickel(II) |
title | (1,10-Phenanthroline-κ(2)
N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ(2)
O,O′)nickel(II) |
title_full | (1,10-Phenanthroline-κ(2)
N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ(2)
O,O′)nickel(II) |
title_fullStr | (1,10-Phenanthroline-κ(2)
N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ(2)
O,O′)nickel(II) |
title_full_unstemmed | (1,10-Phenanthroline-κ(2)
N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ(2)
O,O′)nickel(II) |
title_short | (1,10-Phenanthroline-κ(2)
N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ(2)
O,O′)nickel(II) |
title_sort | (1,10-phenanthroline-κ(2)
n,n′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ(2)
o,o′)nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915153/ https://www.ncbi.nlm.nih.gov/pubmed/21200575 http://dx.doi.org/10.1107/S160053680706672X |
work_keys_str_mv | AT kaitnerbranko 110phenanthrolinek2nnbis2266tetramethylheptane35dionatok2oonickelii AT mesarekkreso 110phenanthrolinek2nnbis2266tetramethylheptane35dionatok2oonickelii AT mestrovicernest 110phenanthrolinek2nnbis2266tetramethylheptane35dionatok2oonickelii |