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(Acetonitrile)[bis­(2-pyridylmeth­yl)amine]bis­(perchlorato)copper(II)

In the title compound, [Cu(ClO(4))(2)(C(12)H(13)N(3))(C(2)H(3)N)], the Cu(II) atom is six-coordinate in a Jahn–Teller distorted octahedral geometry, with coordination by the tridentate chelating ligand, an acetonitrile mol­ecule, and two axial perchlorate anions. The tridentate ligand bis­(2-pyridyl...

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Detalles Bibliográficos
Autores principales: Butcher, Ray J., Tesema, Yohannes T., Yisgedu, Teshome B., Gultneh, Yilma
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915155/
https://www.ncbi.nlm.nih.gov/pubmed/21200577
http://dx.doi.org/10.1107/S1600536807067001
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author Butcher, Ray J.
Tesema, Yohannes T.
Yisgedu, Teshome B.
Gultneh, Yilma
author_facet Butcher, Ray J.
Tesema, Yohannes T.
Yisgedu, Teshome B.
Gultneh, Yilma
author_sort Butcher, Ray J.
collection PubMed
description In the title compound, [Cu(ClO(4))(2)(C(12)H(13)N(3))(C(2)H(3)N)], the Cu(II) atom is six-coordinate in a Jahn–Teller distorted octahedral geometry, with coordination by the tridentate chelating ligand, an acetonitrile mol­ecule, and two axial perchlorate anions. The tridentate ligand bis­(2-pyridylmeth­yl)amine chelates meridionally and equatorially while an acetonitrile mol­ecule is coordinated at the fourth equatorial site. The two perchlorate anions are disordered with site occupancy factors of 0.72/0.28. The amine H is involved in intra­molecular hydrogen bonding to the perchlorate O atoms and there are extensive but weak inter­molecular C—H⋯O inter­actions.
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spelling pubmed-29151552010-12-30 (Acetonitrile)[bis­(2-pyridylmeth­yl)amine]bis­(perchlorato)copper(II) Butcher, Ray J. Tesema, Yohannes T. Yisgedu, Teshome B. Gultneh, Yilma Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(ClO(4))(2)(C(12)H(13)N(3))(C(2)H(3)N)], the Cu(II) atom is six-coordinate in a Jahn–Teller distorted octahedral geometry, with coordination by the tridentate chelating ligand, an acetonitrile mol­ecule, and two axial perchlorate anions. The tridentate ligand bis­(2-pyridylmeth­yl)amine chelates meridionally and equatorially while an acetonitrile mol­ecule is coordinated at the fourth equatorial site. The two perchlorate anions are disordered with site occupancy factors of 0.72/0.28. The amine H is involved in intra­molecular hydrogen bonding to the perchlorate O atoms and there are extensive but weak inter­molecular C—H⋯O inter­actions. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915155/ /pubmed/21200577 http://dx.doi.org/10.1107/S1600536807067001 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Butcher, Ray J.
Tesema, Yohannes T.
Yisgedu, Teshome B.
Gultneh, Yilma
(Acetonitrile)[bis­(2-pyridylmeth­yl)amine]bis­(perchlorato)copper(II)
title (Acetonitrile)[bis­(2-pyridylmeth­yl)amine]bis­(perchlorato)copper(II)
title_full (Acetonitrile)[bis­(2-pyridylmeth­yl)amine]bis­(perchlorato)copper(II)
title_fullStr (Acetonitrile)[bis­(2-pyridylmeth­yl)amine]bis­(perchlorato)copper(II)
title_full_unstemmed (Acetonitrile)[bis­(2-pyridylmeth­yl)amine]bis­(perchlorato)copper(II)
title_short (Acetonitrile)[bis­(2-pyridylmeth­yl)amine]bis­(perchlorato)copper(II)
title_sort (acetonitrile)[bis­(2-pyridylmeth­yl)amine]bis­(perchlorato)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915155/
https://www.ncbi.nlm.nih.gov/pubmed/21200577
http://dx.doi.org/10.1107/S1600536807067001
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