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(Acetonitrile)[bis(2-pyridylmethyl)amine]bis(perchlorato)copper(II)
In the title compound, [Cu(ClO(4))(2)(C(12)H(13)N(3))(C(2)H(3)N)], the Cu(II) atom is six-coordinate in a Jahn–Teller distorted octahedral geometry, with coordination by the tridentate chelating ligand, an acetonitrile molecule, and two axial perchlorate anions. The tridentate ligand bis(2-pyridyl...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915155/ https://www.ncbi.nlm.nih.gov/pubmed/21200577 http://dx.doi.org/10.1107/S1600536807067001 |
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author | Butcher, Ray J. Tesema, Yohannes T. Yisgedu, Teshome B. Gultneh, Yilma |
author_facet | Butcher, Ray J. Tesema, Yohannes T. Yisgedu, Teshome B. Gultneh, Yilma |
author_sort | Butcher, Ray J. |
collection | PubMed |
description | In the title compound, [Cu(ClO(4))(2)(C(12)H(13)N(3))(C(2)H(3)N)], the Cu(II) atom is six-coordinate in a Jahn–Teller distorted octahedral geometry, with coordination by the tridentate chelating ligand, an acetonitrile molecule, and two axial perchlorate anions. The tridentate ligand bis(2-pyridylmethyl)amine chelates meridionally and equatorially while an acetonitrile molecule is coordinated at the fourth equatorial site. The two perchlorate anions are disordered with site occupancy factors of 0.72/0.28. The amine H is involved in intramolecular hydrogen bonding to the perchlorate O atoms and there are extensive but weak intermolecular C—H⋯O interactions. |
format | Text |
id | pubmed-2915155 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29151552010-12-30 (Acetonitrile)[bis(2-pyridylmethyl)amine]bis(perchlorato)copper(II) Butcher, Ray J. Tesema, Yohannes T. Yisgedu, Teshome B. Gultneh, Yilma Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(ClO(4))(2)(C(12)H(13)N(3))(C(2)H(3)N)], the Cu(II) atom is six-coordinate in a Jahn–Teller distorted octahedral geometry, with coordination by the tridentate chelating ligand, an acetonitrile molecule, and two axial perchlorate anions. The tridentate ligand bis(2-pyridylmethyl)amine chelates meridionally and equatorially while an acetonitrile molecule is coordinated at the fourth equatorial site. The two perchlorate anions are disordered with site occupancy factors of 0.72/0.28. The amine H is involved in intramolecular hydrogen bonding to the perchlorate O atoms and there are extensive but weak intermolecular C—H⋯O interactions. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915155/ /pubmed/21200577 http://dx.doi.org/10.1107/S1600536807067001 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Butcher, Ray J. Tesema, Yohannes T. Yisgedu, Teshome B. Gultneh, Yilma (Acetonitrile)[bis(2-pyridylmethyl)amine]bis(perchlorato)copper(II) |
title | (Acetonitrile)[bis(2-pyridylmethyl)amine]bis(perchlorato)copper(II) |
title_full | (Acetonitrile)[bis(2-pyridylmethyl)amine]bis(perchlorato)copper(II) |
title_fullStr | (Acetonitrile)[bis(2-pyridylmethyl)amine]bis(perchlorato)copper(II) |
title_full_unstemmed | (Acetonitrile)[bis(2-pyridylmethyl)amine]bis(perchlorato)copper(II) |
title_short | (Acetonitrile)[bis(2-pyridylmethyl)amine]bis(perchlorato)copper(II) |
title_sort | (acetonitrile)[bis(2-pyridylmethyl)amine]bis(perchlorato)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915155/ https://www.ncbi.nlm.nih.gov/pubmed/21200577 http://dx.doi.org/10.1107/S1600536807067001 |
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