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Tris(propane-1,2-diamine-κ(2) N,N′)nickel(II) tetra­cyanidoplatinate(II)

In the title compound, [Ni(C(3)H(10)N(2))(3)][Pt(CN)(4)], the [Pt(CN)(4)](2−) anion with the environment of the Pt(II) atom, lying on a mirror plane, is square planar, whereas the Ni(II) atom in the [Ni(C(3)N(2)H(10))(3)](2+) cation, also lying on a mirror plane, has a slightly distorted octa­hedral...

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Detalles Bibliográficos
Autores principales: Potočňák, Ivan, Vavra, Martin, Steinborn, Dirk, Wagner, Christoph
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915156/
https://www.ncbi.nlm.nih.gov/pubmed/21200578
http://dx.doi.org/10.1107/S1600536807066913
Descripción
Sumario:In the title compound, [Ni(C(3)H(10)N(2))(3)][Pt(CN)(4)], the [Pt(CN)(4)](2−) anion with the environment of the Pt(II) atom, lying on a mirror plane, is square planar, whereas the Ni(II) atom in the [Ni(C(3)N(2)H(10))(3)](2+) cation, also lying on a mirror plane, has a slightly distorted octa­hedral coordination geometry. Three chiral 1,2-diamino­propane mol­ecules, which are disordered equally over two sets of positions, adopt Δ(δδδ) and Δ(λλλ) configurations. The average Ni—N and Pt—C bond lengths are 2.131 (10) and 1.988 (10) Å, respectively. The cations and anions are connected by N—H⋯N hydrogen bonds.