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Tris(propane-1,2-diamine-κ(2) N,N′)nickel(II) tetracyanidoplatinate(II)
In the title compound, [Ni(C(3)H(10)N(2))(3)][Pt(CN)(4)], the [Pt(CN)(4)](2−) anion with the environment of the Pt(II) atom, lying on a mirror plane, is square planar, whereas the Ni(II) atom in the [Ni(C(3)N(2)H(10))(3)](2+) cation, also lying on a mirror plane, has a slightly distorted octahedral...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2007
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915156/ https://www.ncbi.nlm.nih.gov/pubmed/21200578 http://dx.doi.org/10.1107/S1600536807066913 |
| _version_ | 1782184873561161728 |
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| author | Potočňák, Ivan Vavra, Martin Steinborn, Dirk Wagner, Christoph |
| author_facet | Potočňák, Ivan Vavra, Martin Steinborn, Dirk Wagner, Christoph |
| author_sort | Potočňák, Ivan |
| collection | PubMed |
| description | In the title compound, [Ni(C(3)H(10)N(2))(3)][Pt(CN)(4)], the [Pt(CN)(4)](2−) anion with the environment of the Pt(II) atom, lying on a mirror plane, is square planar, whereas the Ni(II) atom in the [Ni(C(3)N(2)H(10))(3)](2+) cation, also lying on a mirror plane, has a slightly distorted octahedral coordination geometry. Three chiral 1,2-diaminopropane molecules, which are disordered equally over two sets of positions, adopt Δ(δδδ) and Δ(λλλ) configurations. The average Ni—N and Pt—C bond lengths are 2.131 (10) and 1.988 (10) Å, respectively. The cations and anions are connected by N—H⋯N hydrogen bonds. |
| format | Text |
| id | pubmed-2915156 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29151562010-12-30 Tris(propane-1,2-diamine-κ(2) N,N′)nickel(II) tetracyanidoplatinate(II) Potočňák, Ivan Vavra, Martin Steinborn, Dirk Wagner, Christoph Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(3)H(10)N(2))(3)][Pt(CN)(4)], the [Pt(CN)(4)](2−) anion with the environment of the Pt(II) atom, lying on a mirror plane, is square planar, whereas the Ni(II) atom in the [Ni(C(3)N(2)H(10))(3)](2+) cation, also lying on a mirror plane, has a slightly distorted octahedral coordination geometry. Three chiral 1,2-diaminopropane molecules, which are disordered equally over two sets of positions, adopt Δ(δδδ) and Δ(λλλ) configurations. The average Ni—N and Pt—C bond lengths are 2.131 (10) and 1.988 (10) Å, respectively. The cations and anions are connected by N—H⋯N hydrogen bonds. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915156/ /pubmed/21200578 http://dx.doi.org/10.1107/S1600536807066913 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Metal-Organic Papers Potočňák, Ivan Vavra, Martin Steinborn, Dirk Wagner, Christoph Tris(propane-1,2-diamine-κ(2) N,N′)nickel(II) tetracyanidoplatinate(II) |
| title | Tris(propane-1,2-diamine-κ(2)
N,N′)nickel(II) tetracyanidoplatinate(II) |
| title_full | Tris(propane-1,2-diamine-κ(2)
N,N′)nickel(II) tetracyanidoplatinate(II) |
| title_fullStr | Tris(propane-1,2-diamine-κ(2)
N,N′)nickel(II) tetracyanidoplatinate(II) |
| title_full_unstemmed | Tris(propane-1,2-diamine-κ(2)
N,N′)nickel(II) tetracyanidoplatinate(II) |
| title_short | Tris(propane-1,2-diamine-κ(2)
N,N′)nickel(II) tetracyanidoplatinate(II) |
| title_sort | tris(propane-1,2-diamine-κ(2)
n,n′)nickel(ii) tetracyanidoplatinate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915156/ https://www.ncbi.nlm.nih.gov/pubmed/21200578 http://dx.doi.org/10.1107/S1600536807066913 |
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