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Bis(2,2′-bipyridine)(5,5′-iminoditetrazolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate
The title complex, [Cd(C(2)HN(9))(C(10)H(8)N(2))(2)]·0.5C(10)H(8)N(2)·H(2)O, was prepared under hydrothermal reaction conditions. The asymmetric unit contains the cadmium complex, half a 2,2′-bipyridine solvent molecule and a solvent water molecule. The Cd(II) ion is coordinated by four N atoms f...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915158/ https://www.ncbi.nlm.nih.gov/pubmed/21200580 http://dx.doi.org/10.1107/S1600536807066846 |
Sumario: | The title complex, [Cd(C(2)HN(9))(C(10)H(8)N(2))(2)]·0.5C(10)H(8)N(2)·H(2)O, was prepared under hydrothermal reaction conditions. The asymmetric unit contains the cadmium complex, half a 2,2′-bipyridine solvent molecule and a solvent water molecule. The Cd(II) ion is coordinated by four N atoms from two 2,2′-bipyridine ligands and two N atoms from an HBTA(−) anion ligand [where H(2)BTA is N,N-bis(1H-tetrazol-5-yl)amine], forming an octahedral geometry. The complex is linked into a three-dimensional network by O—H⋯N and N—H⋯N hydrogen bonds and by the stacking interactions of rings, with distances of 3.5–3.7 Å between the atoms of two parallel 2,2′-bipyridine rings. |
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