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Bis(2,2′-bipyridine)(5,5′-imino­ditetra­zolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate

The title complex, [Cd(C(2)HN(9))(C(10)H(8)N(2))(2)]·0.5C(10)H(8)N(2)·H(2)O, was prepared under hydro­thermal reaction conditions. The asymmetric unit contains the cadmium complex, half a 2,2′-bipyridine solvent mol­ecule and a solvent water mol­ecule. The Cd(II) ion is coordinated by four N atoms f...

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Detalles Bibliográficos
Autores principales: Lin, Jiao-Min, Guan, Yang-Fan, Dong, Wen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915158/
https://www.ncbi.nlm.nih.gov/pubmed/21200580
http://dx.doi.org/10.1107/S1600536807066846
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author Lin, Jiao-Min
Guan, Yang-Fan
Dong, Wen
author_facet Lin, Jiao-Min
Guan, Yang-Fan
Dong, Wen
author_sort Lin, Jiao-Min
collection PubMed
description The title complex, [Cd(C(2)HN(9))(C(10)H(8)N(2))(2)]·0.5C(10)H(8)N(2)·H(2)O, was prepared under hydro­thermal reaction conditions. The asymmetric unit contains the cadmium complex, half a 2,2′-bipyridine solvent mol­ecule and a solvent water mol­ecule. The Cd(II) ion is coordinated by four N atoms from two 2,2′-bipyridine ligands and two N atoms from an HBTA(−) anion ligand [where H(2)BTA is N,N-bis­(1H-tetra­zol-5-yl)amine], forming an octa­hedral geometry. The complex is linked into a three-dimensional network by O—H⋯N and N—H⋯N hydrogen bonds and by the stacking inter­actions of rings, with distances of 3.5–3.7 Å between the atoms of two parallel 2,2′-bipyridine rings.
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spelling pubmed-29151582010-12-30 Bis(2,2′-bipyridine)(5,5′-imino­ditetra­zolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate Lin, Jiao-Min Guan, Yang-Fan Dong, Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cd(C(2)HN(9))(C(10)H(8)N(2))(2)]·0.5C(10)H(8)N(2)·H(2)O, was prepared under hydro­thermal reaction conditions. The asymmetric unit contains the cadmium complex, half a 2,2′-bipyridine solvent mol­ecule and a solvent water mol­ecule. The Cd(II) ion is coordinated by four N atoms from two 2,2′-bipyridine ligands and two N atoms from an HBTA(−) anion ligand [where H(2)BTA is N,N-bis­(1H-tetra­zol-5-yl)amine], forming an octa­hedral geometry. The complex is linked into a three-dimensional network by O—H⋯N and N—H⋯N hydrogen bonds and by the stacking inter­actions of rings, with distances of 3.5–3.7 Å between the atoms of two parallel 2,2′-bipyridine rings. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915158/ /pubmed/21200580 http://dx.doi.org/10.1107/S1600536807066846 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Lin, Jiao-Min
Guan, Yang-Fan
Dong, Wen
Bis(2,2′-bipyridine)(5,5′-imino­ditetra­zolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate
title Bis(2,2′-bipyridine)(5,5′-imino­ditetra­zolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate
title_full Bis(2,2′-bipyridine)(5,5′-imino­ditetra­zolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate
title_fullStr Bis(2,2′-bipyridine)(5,5′-imino­ditetra­zolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate
title_full_unstemmed Bis(2,2′-bipyridine)(5,5′-imino­ditetra­zolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate
title_short Bis(2,2′-bipyridine)(5,5′-imino­ditetra­zolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate
title_sort bis(2,2′-bipyridine)(5,5′-imino­ditetra­zolato)cadmium(ii) 2,2′-bipyridine hemisolvate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915158/
https://www.ncbi.nlm.nih.gov/pubmed/21200580
http://dx.doi.org/10.1107/S1600536807066846
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AT dongwen bis22bipyridine55iminoditetrazolatocadmiumii22bipyridinehemisolvatemonohydrate