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Bis(2,2′-bipyridine)(5,5′-iminoditetrazolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate
The title complex, [Cd(C(2)HN(9))(C(10)H(8)N(2))(2)]·0.5C(10)H(8)N(2)·H(2)O, was prepared under hydrothermal reaction conditions. The asymmetric unit contains the cadmium complex, half a 2,2′-bipyridine solvent molecule and a solvent water molecule. The Cd(II) ion is coordinated by four N atoms f...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915158/ https://www.ncbi.nlm.nih.gov/pubmed/21200580 http://dx.doi.org/10.1107/S1600536807066846 |
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author | Lin, Jiao-Min Guan, Yang-Fan Dong, Wen |
author_facet | Lin, Jiao-Min Guan, Yang-Fan Dong, Wen |
author_sort | Lin, Jiao-Min |
collection | PubMed |
description | The title complex, [Cd(C(2)HN(9))(C(10)H(8)N(2))(2)]·0.5C(10)H(8)N(2)·H(2)O, was prepared under hydrothermal reaction conditions. The asymmetric unit contains the cadmium complex, half a 2,2′-bipyridine solvent molecule and a solvent water molecule. The Cd(II) ion is coordinated by four N atoms from two 2,2′-bipyridine ligands and two N atoms from an HBTA(−) anion ligand [where H(2)BTA is N,N-bis(1H-tetrazol-5-yl)amine], forming an octahedral geometry. The complex is linked into a three-dimensional network by O—H⋯N and N—H⋯N hydrogen bonds and by the stacking interactions of rings, with distances of 3.5–3.7 Å between the atoms of two parallel 2,2′-bipyridine rings. |
format | Text |
id | pubmed-2915158 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29151582010-12-30 Bis(2,2′-bipyridine)(5,5′-iminoditetrazolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate Lin, Jiao-Min Guan, Yang-Fan Dong, Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cd(C(2)HN(9))(C(10)H(8)N(2))(2)]·0.5C(10)H(8)N(2)·H(2)O, was prepared under hydrothermal reaction conditions. The asymmetric unit contains the cadmium complex, half a 2,2′-bipyridine solvent molecule and a solvent water molecule. The Cd(II) ion is coordinated by four N atoms from two 2,2′-bipyridine ligands and two N atoms from an HBTA(−) anion ligand [where H(2)BTA is N,N-bis(1H-tetrazol-5-yl)amine], forming an octahedral geometry. The complex is linked into a three-dimensional network by O—H⋯N and N—H⋯N hydrogen bonds and by the stacking interactions of rings, with distances of 3.5–3.7 Å between the atoms of two parallel 2,2′-bipyridine rings. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915158/ /pubmed/21200580 http://dx.doi.org/10.1107/S1600536807066846 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Lin, Jiao-Min Guan, Yang-Fan Dong, Wen Bis(2,2′-bipyridine)(5,5′-iminoditetrazolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate |
title | Bis(2,2′-bipyridine)(5,5′-iminoditetrazolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate |
title_full | Bis(2,2′-bipyridine)(5,5′-iminoditetrazolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate |
title_fullStr | Bis(2,2′-bipyridine)(5,5′-iminoditetrazolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate |
title_full_unstemmed | Bis(2,2′-bipyridine)(5,5′-iminoditetrazolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate |
title_short | Bis(2,2′-bipyridine)(5,5′-iminoditetrazolato)cadmium(II) 2,2′-bipyridine hemisolvate monohydrate |
title_sort | bis(2,2′-bipyridine)(5,5′-iminoditetrazolato)cadmium(ii) 2,2′-bipyridine hemisolvate monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915158/ https://www.ncbi.nlm.nih.gov/pubmed/21200580 http://dx.doi.org/10.1107/S1600536807066846 |
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