trans-Bis[1,2-bis­(dimethyl­phosphino)­ethane]­bromido­nitrosyl­tungsten(0)

The crystal structure of the title compound, [WBr(NO)(C(6)H(16)P(2))(2)], reveals a distorted octa­hedral geometry around the W centre. The W atom lies on a special position at an inversion centre (the Br and NO ligands are equally disordered). The bis­(dimethyl­phosphino)ethane ligand is also sever...

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Detalles Bibliográficos
Autores principales: Avramović, Nataša, Blacque, Olivier, Berke, Heinz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915161/
https://www.ncbi.nlm.nih.gov/pubmed/21200584
http://dx.doi.org/10.1107/S1600536807067189
Descripción
Sumario:The crystal structure of the title compound, [WBr(NO)(C(6)H(16)P(2))(2)], reveals a distorted octa­hedral geometry around the W centre. The W atom lies on a special position at an inversion centre (the Br and NO ligands are equally disordered). The bis­(dimethyl­phosphino)ethane ligand is also severely disordered (site occupancy factors 0.52 and 0.48). This is the first structure of a tungsten species with nitrosyl and bromide ligands.

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