trans-Bis[1,2-bis­(dimethyl­phosphino)­ethane]­bromido­nitrosyl­tungsten(0)

The crystal structure of the title compound, [WBr(NO)(C(6)H(16)P(2))(2)], reveals a distorted octa­hedral geometry around the W centre. The W atom lies on a special position at an inversion centre (the Br and NO ligands are equally disordered). The bis­(dimethyl­phosphino)ethane ligand is also sever...

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Detalles Bibliográficos
Autores principales: Avramović, Nataša, Blacque, Olivier, Berke, Heinz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915161/
https://www.ncbi.nlm.nih.gov/pubmed/21200584
http://dx.doi.org/10.1107/S1600536807067189
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author Avramović, Nataša
Blacque, Olivier
Berke, Heinz
author_facet Avramović, Nataša
Blacque, Olivier
Berke, Heinz
author_sort Avramović, Nataša
collection PubMed
description The crystal structure of the title compound, [WBr(NO)(C(6)H(16)P(2))(2)], reveals a distorted octa­hedral geometry around the W centre. The W atom lies on a special position at an inversion centre (the Br and NO ligands are equally disordered). The bis­(dimethyl­phosphino)ethane ligand is also severely disordered (site occupancy factors 0.52 and 0.48). This is the first structure of a tungsten species with nitrosyl and bromide ligands.
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spelling pubmed-29151612010-12-30 trans-Bis[1,2-bis­(dimethyl­phosphino)­ethane]­bromido­nitrosyl­tungsten(0) Avramović, Nataša Blacque, Olivier Berke, Heinz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [WBr(NO)(C(6)H(16)P(2))(2)], reveals a distorted octa­hedral geometry around the W centre. The W atom lies on a special position at an inversion centre (the Br and NO ligands are equally disordered). The bis­(dimethyl­phosphino)ethane ligand is also severely disordered (site occupancy factors 0.52 and 0.48). This is the first structure of a tungsten species with nitrosyl and bromide ligands. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915161/ /pubmed/21200584 http://dx.doi.org/10.1107/S1600536807067189 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Avramović, Nataša
Blacque, Olivier
Berke, Heinz
trans-Bis[1,2-bis­(dimethyl­phosphino)­ethane]­bromido­nitrosyl­tungsten(0)
title trans-Bis[1,2-bis­(dimethyl­phosphino)­ethane]­bromido­nitrosyl­tungsten(0)
title_full trans-Bis[1,2-bis­(dimethyl­phosphino)­ethane]­bromido­nitrosyl­tungsten(0)
title_fullStr trans-Bis[1,2-bis­(dimethyl­phosphino)­ethane]­bromido­nitrosyl­tungsten(0)
title_full_unstemmed trans-Bis[1,2-bis­(dimethyl­phosphino)­ethane]­bromido­nitrosyl­tungsten(0)
title_short trans-Bis[1,2-bis­(dimethyl­phosphino)­ethane]­bromido­nitrosyl­tungsten(0)
title_sort trans-bis[1,2-bis­(dimethyl­phosphino)­ethane]­bromido­nitrosyl­tungsten(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915161/
https://www.ncbi.nlm.nih.gov/pubmed/21200584
http://dx.doi.org/10.1107/S1600536807067189
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AT blacqueolivier transbis12bisdimethylphosphinoethanebromidonitrosyltungsten0
AT berkeheinz transbis12bisdimethylphosphinoethanebromidonitrosyltungsten0

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