Bis[1,2-bis­(dimethyl­phosphino)­ethane]­dichloridonitro­syltungsten(0) chloride

In the crystal structure of the title compound, [WCl(2)(NO)(C(6)H(16)P(2))(2)]Cl, the seven-coordinated tungsten(II) center displays a distorted penta­gonal–bipyramidal geometry with trans nitrosyl and chloride ligands. The NO and Cl ligands are disordered over two positions; the site occupancy fact...

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Detalles Bibliográficos
Autores principales: Avramović, Nataša, Blacque, Olivier, Schmalle, Helmut W., Berke, Heinz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915163/
https://www.ncbi.nlm.nih.gov/pubmed/21200586
http://dx.doi.org/10.1107/S1600536807067128
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author Avramović, Nataša
Blacque, Olivier
Schmalle, Helmut W.
Berke, Heinz
author_facet Avramović, Nataša
Blacque, Olivier
Schmalle, Helmut W.
Berke, Heinz
author_sort Avramović, Nataša
collection PubMed
description In the crystal structure of the title compound, [WCl(2)(NO)(C(6)H(16)P(2))(2)]Cl, the seven-coordinated tungsten(II) center displays a distorted penta­gonal–bipyramidal geometry with trans nitrosyl and chloride ligands. The NO and Cl ligands are disordered over two positions; the site occupancy factors are 0.6 and 0.4.
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spelling pubmed-29151632010-12-30 Bis[1,2-bis­(dimethyl­phosphino)­ethane]­dichloridonitro­syltungsten(0) chloride Avramović, Nataša Blacque, Olivier Schmalle, Helmut W. Berke, Heinz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [WCl(2)(NO)(C(6)H(16)P(2))(2)]Cl, the seven-coordinated tungsten(II) center displays a distorted penta­gonal–bipyramidal geometry with trans nitrosyl and chloride ligands. The NO and Cl ligands are disordered over two positions; the site occupancy factors are 0.6 and 0.4. International Union of Crystallography 2007-12-22 /pmc/articles/PMC2915163/ /pubmed/21200586 http://dx.doi.org/10.1107/S1600536807067128 Text en © Avramović et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Avramović, Nataša
Blacque, Olivier
Schmalle, Helmut W.
Berke, Heinz
Bis[1,2-bis­(dimethyl­phosphino)­ethane]­dichloridonitro­syltungsten(0) chloride
title Bis[1,2-bis­(dimethyl­phosphino)­ethane]­dichloridonitro­syltungsten(0) chloride
title_full Bis[1,2-bis­(dimethyl­phosphino)­ethane]­dichloridonitro­syltungsten(0) chloride
title_fullStr Bis[1,2-bis­(dimethyl­phosphino)­ethane]­dichloridonitro­syltungsten(0) chloride
title_full_unstemmed Bis[1,2-bis­(dimethyl­phosphino)­ethane]­dichloridonitro­syltungsten(0) chloride
title_short Bis[1,2-bis­(dimethyl­phosphino)­ethane]­dichloridonitro­syltungsten(0) chloride
title_sort bis[1,2-bis­(dimethyl­phosphino)­ethane]­dichloridonitro­syltungsten(0) chloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915163/
https://www.ncbi.nlm.nih.gov/pubmed/21200586
http://dx.doi.org/10.1107/S1600536807067128
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AT blacqueolivier bis12bisdimethylphosphinoethanedichloridonitrosyltungsten0chloride
AT schmallehelmutw bis12bisdimethylphosphinoethanedichloridonitrosyltungsten0chloride
AT berkeheinz bis12bisdimethylphosphinoethanedichloridonitrosyltungsten0chloride

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