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catena-Poly[bis­(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate]

In the title compound, {(C(10)H(12)N(3)O(3)S)(2)[CdCl(4)]·H(2)O}(n), the Cd(II) atom is five-coordinate with a distorted trigonal–bipyramidal geometry formed by chloride ions. The Cd atom and two of the Cl atoms lie on a mirror plane. The cation is protonated on the amino group N atom; it is not coo...

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Detalles Bibliográficos
Autores principales: Subashini, Annamalai, Muthiah, Packianathan Thomas, Bocelli, Gabriele, Cantoni, Andrea
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915166/
https://www.ncbi.nlm.nih.gov/pubmed/21200590
http://dx.doi.org/10.1107/S1600536807067190
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author Subashini, Annamalai
Muthiah, Packianathan Thomas
Bocelli, Gabriele
Cantoni, Andrea
author_facet Subashini, Annamalai
Muthiah, Packianathan Thomas
Bocelli, Gabriele
Cantoni, Andrea
author_sort Subashini, Annamalai
collection PubMed
description In the title compound, {(C(10)H(12)N(3)O(3)S)(2)[CdCl(4)]·H(2)O}(n), the Cd(II) atom is five-coordinate with a distorted trigonal–bipyramidal geometry formed by chloride ions. The Cd atom and two of the Cl atoms lie on a mirror plane. The cation is protonated on the amino group N atom; it is not coordinated to cadmium, but is hydrogen bonded to the chlorido ligands. Each water mol­ecule bridges two chlorido ligands, generating ring motifs along the –Cd—Cl—Cd– chains. The isoxazole unit and the amide groups are linked through a pair of N—H⋯N hydrogen bonds. The crystal structure is stabilized by N—H⋯O, O—H⋯Cl, C—H⋯N, N—H⋯Cl and C—H⋯O hydrogen bonds.
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spelling pubmed-29151662010-12-30 catena-Poly[bis­(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate] Subashini, Annamalai Muthiah, Packianathan Thomas Bocelli, Gabriele Cantoni, Andrea Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {(C(10)H(12)N(3)O(3)S)(2)[CdCl(4)]·H(2)O}(n), the Cd(II) atom is five-coordinate with a distorted trigonal–bipyramidal geometry formed by chloride ions. The Cd atom and two of the Cl atoms lie on a mirror plane. The cation is protonated on the amino group N atom; it is not coordinated to cadmium, but is hydrogen bonded to the chlorido ligands. Each water mol­ecule bridges two chlorido ligands, generating ring motifs along the –Cd—Cl—Cd– chains. The isoxazole unit and the amide groups are linked through a pair of N—H⋯N hydrogen bonds. The crystal structure is stabilized by N—H⋯O, O—H⋯Cl, C—H⋯N, N—H⋯Cl and C—H⋯O hydrogen bonds. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915166/ /pubmed/21200590 http://dx.doi.org/10.1107/S1600536807067190 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Subashini, Annamalai
Muthiah, Packianathan Thomas
Bocelli, Gabriele
Cantoni, Andrea
catena-Poly[bis­(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate]
title catena-Poly[bis­(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate]
title_full catena-Poly[bis­(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate]
title_fullStr catena-Poly[bis­(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate]
title_full_unstemmed catena-Poly[bis­(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate]
title_short catena-Poly[bis­(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate]
title_sort catena-poly[bis­(sulfamethoxazolium) [[trichloridocadmate(ii)]-μ-chlorido] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915166/
https://www.ncbi.nlm.nih.gov/pubmed/21200590
http://dx.doi.org/10.1107/S1600536807067190
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