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catena-Poly[bis(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate]
In the title compound, {(C(10)H(12)N(3)O(3)S)(2)[CdCl(4)]·H(2)O}(n), the Cd(II) atom is five-coordinate with a distorted trigonal–bipyramidal geometry formed by chloride ions. The Cd atom and two of the Cl atoms lie on a mirror plane. The cation is protonated on the amino group N atom; it is not coo...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915166/ https://www.ncbi.nlm.nih.gov/pubmed/21200590 http://dx.doi.org/10.1107/S1600536807067190 |
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author | Subashini, Annamalai Muthiah, Packianathan Thomas Bocelli, Gabriele Cantoni, Andrea |
author_facet | Subashini, Annamalai Muthiah, Packianathan Thomas Bocelli, Gabriele Cantoni, Andrea |
author_sort | Subashini, Annamalai |
collection | PubMed |
description | In the title compound, {(C(10)H(12)N(3)O(3)S)(2)[CdCl(4)]·H(2)O}(n), the Cd(II) atom is five-coordinate with a distorted trigonal–bipyramidal geometry formed by chloride ions. The Cd atom and two of the Cl atoms lie on a mirror plane. The cation is protonated on the amino group N atom; it is not coordinated to cadmium, but is hydrogen bonded to the chlorido ligands. Each water molecule bridges two chlorido ligands, generating ring motifs along the –Cd—Cl—Cd– chains. The isoxazole unit and the amide groups are linked through a pair of N—H⋯N hydrogen bonds. The crystal structure is stabilized by N—H⋯O, O—H⋯Cl, C—H⋯N, N—H⋯Cl and C—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2915166 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29151662010-12-30 catena-Poly[bis(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate] Subashini, Annamalai Muthiah, Packianathan Thomas Bocelli, Gabriele Cantoni, Andrea Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {(C(10)H(12)N(3)O(3)S)(2)[CdCl(4)]·H(2)O}(n), the Cd(II) atom is five-coordinate with a distorted trigonal–bipyramidal geometry formed by chloride ions. The Cd atom and two of the Cl atoms lie on a mirror plane. The cation is protonated on the amino group N atom; it is not coordinated to cadmium, but is hydrogen bonded to the chlorido ligands. Each water molecule bridges two chlorido ligands, generating ring motifs along the –Cd—Cl—Cd– chains. The isoxazole unit and the amide groups are linked through a pair of N—H⋯N hydrogen bonds. The crystal structure is stabilized by N—H⋯O, O—H⋯Cl, C—H⋯N, N—H⋯Cl and C—H⋯O hydrogen bonds. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915166/ /pubmed/21200590 http://dx.doi.org/10.1107/S1600536807067190 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Subashini, Annamalai Muthiah, Packianathan Thomas Bocelli, Gabriele Cantoni, Andrea catena-Poly[bis(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate] |
title |
catena-Poly[bis(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate] |
title_full |
catena-Poly[bis(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate] |
title_fullStr |
catena-Poly[bis(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate] |
title_full_unstemmed |
catena-Poly[bis(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate] |
title_short |
catena-Poly[bis(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate] |
title_sort | catena-poly[bis(sulfamethoxazolium) [[trichloridocadmate(ii)]-μ-chlorido] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915166/ https://www.ncbi.nlm.nih.gov/pubmed/21200590 http://dx.doi.org/10.1107/S1600536807067190 |
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