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(Benzoato-κ(2) O,O′)(quinoline-2-carboxylato-κ(2) N,O)(quinoline-2-carboxylic acid-κ(2) N,O)manganese(II)
The crystal structure of the title compound, [Mn(C(7)H(5)O(2))(C(10)H(6)NO(2))(C(10)H(7)NO(2))], contains manganese(II) ions six-coordinated in a distorted octahedral environment. The equatorial plane is occupied by four O atoms, two from the carboxylate group of the benzoate ion, the other two fr...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915171/ https://www.ncbi.nlm.nih.gov/pubmed/21200595 http://dx.doi.org/10.1107/S1600536807066809 |
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author | Martins, Nuno D. Silva, Joana A. Ramos Silva, Manuela Matos Beja, Ana Sobral, Abilio J. F.N. |
author_facet | Martins, Nuno D. Silva, Joana A. Ramos Silva, Manuela Matos Beja, Ana Sobral, Abilio J. F.N. |
author_sort | Martins, Nuno D. |
collection | PubMed |
description | The crystal structure of the title compound, [Mn(C(7)H(5)O(2))(C(10)H(6)NO(2))(C(10)H(7)NO(2))], contains manganese(II) ions six-coordinated in a distorted octahedral environment. The equatorial plane is occupied by four O atoms, two from the carboxylate group of the benzoate ion, the other two from carboxylate/carboxyl groups of the quinaldate/quinaldic acid molecules. The axial positions are occupied by the N atoms of the quinoline ring systems. The metal ion lies on a twofold rotation axis that bisects the benzoate ligand; the quinaldate and quinaldic acid ligands are therefore equivalent by symmetry, and the carboxylate/carboxyl groups are disordered. The complexes are joined together by hydrogen bonds between the carboxylate/carboxyl groups of adjacent quinaldate/quinaldic acid molecules, forming zigzag chains that run along the c axis. |
format | Text |
id | pubmed-2915171 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29151712010-12-30 (Benzoato-κ(2) O,O′)(quinoline-2-carboxylato-κ(2) N,O)(quinoline-2-carboxylic acid-κ(2) N,O)manganese(II) Martins, Nuno D. Silva, Joana A. Ramos Silva, Manuela Matos Beja, Ana Sobral, Abilio J. F.N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Mn(C(7)H(5)O(2))(C(10)H(6)NO(2))(C(10)H(7)NO(2))], contains manganese(II) ions six-coordinated in a distorted octahedral environment. The equatorial plane is occupied by four O atoms, two from the carboxylate group of the benzoate ion, the other two from carboxylate/carboxyl groups of the quinaldate/quinaldic acid molecules. The axial positions are occupied by the N atoms of the quinoline ring systems. The metal ion lies on a twofold rotation axis that bisects the benzoate ligand; the quinaldate and quinaldic acid ligands are therefore equivalent by symmetry, and the carboxylate/carboxyl groups are disordered. The complexes are joined together by hydrogen bonds between the carboxylate/carboxyl groups of adjacent quinaldate/quinaldic acid molecules, forming zigzag chains that run along the c axis. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915171/ /pubmed/21200595 http://dx.doi.org/10.1107/S1600536807066809 Text en © Martins et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Martins, Nuno D. Silva, Joana A. Ramos Silva, Manuela Matos Beja, Ana Sobral, Abilio J. F.N. (Benzoato-κ(2) O,O′)(quinoline-2-carboxylato-κ(2) N,O)(quinoline-2-carboxylic acid-κ(2) N,O)manganese(II) |
title | (Benzoato-κ(2)
O,O′)(quinoline-2-carboxylato-κ(2)
N,O)(quinoline-2-carboxylic acid-κ(2)
N,O)manganese(II) |
title_full | (Benzoato-κ(2)
O,O′)(quinoline-2-carboxylato-κ(2)
N,O)(quinoline-2-carboxylic acid-κ(2)
N,O)manganese(II) |
title_fullStr | (Benzoato-κ(2)
O,O′)(quinoline-2-carboxylato-κ(2)
N,O)(quinoline-2-carboxylic acid-κ(2)
N,O)manganese(II) |
title_full_unstemmed | (Benzoato-κ(2)
O,O′)(quinoline-2-carboxylato-κ(2)
N,O)(quinoline-2-carboxylic acid-κ(2)
N,O)manganese(II) |
title_short | (Benzoato-κ(2)
O,O′)(quinoline-2-carboxylato-κ(2)
N,O)(quinoline-2-carboxylic acid-κ(2)
N,O)manganese(II) |
title_sort | (benzoato-κ(2)
o,o′)(quinoline-2-carboxylato-κ(2)
n,o)(quinoline-2-carboxylic acid-κ(2)
n,o)manganese(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915171/ https://www.ncbi.nlm.nih.gov/pubmed/21200595 http://dx.doi.org/10.1107/S1600536807066809 |
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