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(Benzoato-κ(2) O,O′)(quinoline-2-carboxyl­ato-κ(2) N,O)(quinoline-2-carboxylic acid-κ(2) N,O)manganese(II)

The crystal structure of the title compound, [Mn(C(7)H(5)O(2))(C(10)H(6)NO(2))(C(10)H(7)NO(2))], contains manganese(II) ions six-coordinated in a distorted octa­hedral environment. The equatorial plane is occupied by four O atoms, two from the carboxyl­ate group of the benzoate ion, the other two fr...

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Autores principales: Martins, Nuno D., Silva, Joana A., Ramos Silva, Manuela, Matos Beja, Ana, Sobral, Abilio J. F.N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915171/
https://www.ncbi.nlm.nih.gov/pubmed/21200595
http://dx.doi.org/10.1107/S1600536807066809
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author Martins, Nuno D.
Silva, Joana A.
Ramos Silva, Manuela
Matos Beja, Ana
Sobral, Abilio J. F.N.
author_facet Martins, Nuno D.
Silva, Joana A.
Ramos Silva, Manuela
Matos Beja, Ana
Sobral, Abilio J. F.N.
author_sort Martins, Nuno D.
collection PubMed
description The crystal structure of the title compound, [Mn(C(7)H(5)O(2))(C(10)H(6)NO(2))(C(10)H(7)NO(2))], contains manganese(II) ions six-coordinated in a distorted octa­hedral environment. The equatorial plane is occupied by four O atoms, two from the carboxyl­ate group of the benzoate ion, the other two from carboxyl­ate/carboxyl groups of the quinaldate/quinaldic acid mol­ecules. The axial positions are occupied by the N atoms of the quinoline ring systems. The metal ion lies on a twofold rotation axis that bisects the benzoate ligand; the quinaldate and quinaldic acid ligands are therefore equivalent by symmetry, and the carboxylate/carboxyl groups are disordered. The complexes are joined together by hydrogen bonds between the carboxyl­ate/carboxyl groups of adjacent quinaldate/quinaldic acid mol­ecules, forming zigzag chains that run along the c axis.
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spelling pubmed-29151712010-12-30 (Benzoato-κ(2) O,O′)(quinoline-2-carboxyl­ato-κ(2) N,O)(quinoline-2-carboxylic acid-κ(2) N,O)manganese(II) Martins, Nuno D. Silva, Joana A. Ramos Silva, Manuela Matos Beja, Ana Sobral, Abilio J. F.N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Mn(C(7)H(5)O(2))(C(10)H(6)NO(2))(C(10)H(7)NO(2))], contains manganese(II) ions six-coordinated in a distorted octa­hedral environment. The equatorial plane is occupied by four O atoms, two from the carboxyl­ate group of the benzoate ion, the other two from carboxyl­ate/carboxyl groups of the quinaldate/quinaldic acid mol­ecules. The axial positions are occupied by the N atoms of the quinoline ring systems. The metal ion lies on a twofold rotation axis that bisects the benzoate ligand; the quinaldate and quinaldic acid ligands are therefore equivalent by symmetry, and the carboxylate/carboxyl groups are disordered. The complexes are joined together by hydrogen bonds between the carboxyl­ate/carboxyl groups of adjacent quinaldate/quinaldic acid mol­ecules, forming zigzag chains that run along the c axis. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915171/ /pubmed/21200595 http://dx.doi.org/10.1107/S1600536807066809 Text en © Martins et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Martins, Nuno D.
Silva, Joana A.
Ramos Silva, Manuela
Matos Beja, Ana
Sobral, Abilio J. F.N.
(Benzoato-κ(2) O,O′)(quinoline-2-carboxyl­ato-κ(2) N,O)(quinoline-2-carboxylic acid-κ(2) N,O)manganese(II)
title (Benzoato-κ(2) O,O′)(quinoline-2-carboxyl­ato-κ(2) N,O)(quinoline-2-carboxylic acid-κ(2) N,O)manganese(II)
title_full (Benzoato-κ(2) O,O′)(quinoline-2-carboxyl­ato-κ(2) N,O)(quinoline-2-carboxylic acid-κ(2) N,O)manganese(II)
title_fullStr (Benzoato-κ(2) O,O′)(quinoline-2-carboxyl­ato-κ(2) N,O)(quinoline-2-carboxylic acid-κ(2) N,O)manganese(II)
title_full_unstemmed (Benzoato-κ(2) O,O′)(quinoline-2-carboxyl­ato-κ(2) N,O)(quinoline-2-carboxylic acid-κ(2) N,O)manganese(II)
title_short (Benzoato-κ(2) O,O′)(quinoline-2-carboxyl­ato-κ(2) N,O)(quinoline-2-carboxylic acid-κ(2) N,O)manganese(II)
title_sort (benzoato-κ(2) o,o′)(quinoline-2-carboxyl­ato-κ(2) n,o)(quinoline-2-carboxylic acid-κ(2) n,o)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915171/
https://www.ncbi.nlm.nih.gov/pubmed/21200595
http://dx.doi.org/10.1107/S1600536807066809
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