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Poly[diaquabis(2,2′-bipyridine)tris(μ(4)-2,2′-bipyridine-4,4′-dicarboxylato)dineodymium(III)]
In the crystal structure of the title mixed-ligand coordination polymer, [Nd(2)(C(12)H(6)N(2)O(4))(3)(C(10)H(8)N(2))(2)(H(2)O)(2)](n), the Nd(III) ion is in an octahedral coordination environment formed by one water molecule, one chelating 2,2′-bipyridine ligand, and five monodentate carboxylate...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915173/ https://www.ncbi.nlm.nih.gov/pubmed/21200598 http://dx.doi.org/10.1107/S1600536807067396 |
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author | Tsai, Chia-Jung Liu, Yen-Hsiang |
author_facet | Tsai, Chia-Jung Liu, Yen-Hsiang |
author_sort | Tsai, Chia-Jung |
collection | PubMed |
description | In the crystal structure of the title mixed-ligand coordination polymer, [Nd(2)(C(12)H(6)N(2)O(4))(3)(C(10)H(8)N(2))(2)(H(2)O)(2)](n), the Nd(III) ion is in an octahedral coordination environment formed by one water molecule, one chelating 2,2′-bipyridine ligand, and five monodentate carboxylate groups. The local coordination polyhedron around the Nd(III) ion is a bicapped trigonal prism. Two Nd(III) centers are bridged by four carboxylate groups to form an Nd(2) dimeric unit; these are further connected by 2,2′-bipyridine-4,4′-dicarboxylate linkers, resulting in a layered coordination network. |
format | Text |
id | pubmed-2915173 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29151732010-12-30 Poly[diaquabis(2,2′-bipyridine)tris(μ(4)-2,2′-bipyridine-4,4′-dicarboxylato)dineodymium(III)] Tsai, Chia-Jung Liu, Yen-Hsiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title mixed-ligand coordination polymer, [Nd(2)(C(12)H(6)N(2)O(4))(3)(C(10)H(8)N(2))(2)(H(2)O)(2)](n), the Nd(III) ion is in an octahedral coordination environment formed by one water molecule, one chelating 2,2′-bipyridine ligand, and five monodentate carboxylate groups. The local coordination polyhedron around the Nd(III) ion is a bicapped trigonal prism. Two Nd(III) centers are bridged by four carboxylate groups to form an Nd(2) dimeric unit; these are further connected by 2,2′-bipyridine-4,4′-dicarboxylate linkers, resulting in a layered coordination network. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915173/ /pubmed/21200598 http://dx.doi.org/10.1107/S1600536807067396 Text en © Tsai and Liu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tsai, Chia-Jung Liu, Yen-Hsiang Poly[diaquabis(2,2′-bipyridine)tris(μ(4)-2,2′-bipyridine-4,4′-dicarboxylato)dineodymium(III)] |
title | Poly[diaquabis(2,2′-bipyridine)tris(μ(4)-2,2′-bipyridine-4,4′-dicarboxylato)dineodymium(III)] |
title_full | Poly[diaquabis(2,2′-bipyridine)tris(μ(4)-2,2′-bipyridine-4,4′-dicarboxylato)dineodymium(III)] |
title_fullStr | Poly[diaquabis(2,2′-bipyridine)tris(μ(4)-2,2′-bipyridine-4,4′-dicarboxylato)dineodymium(III)] |
title_full_unstemmed | Poly[diaquabis(2,2′-bipyridine)tris(μ(4)-2,2′-bipyridine-4,4′-dicarboxylato)dineodymium(III)] |
title_short | Poly[diaquabis(2,2′-bipyridine)tris(μ(4)-2,2′-bipyridine-4,4′-dicarboxylato)dineodymium(III)] |
title_sort | poly[diaquabis(2,2′-bipyridine)tris(μ(4)-2,2′-bipyridine-4,4′-dicarboxylato)dineodymium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915173/ https://www.ncbi.nlm.nih.gov/pubmed/21200598 http://dx.doi.org/10.1107/S1600536807067396 |
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