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Poly[diaqua­bis(2,2′-bipyridine)tris­(μ(4)-2,2′-bipyridine-4,4′-dicarboxyl­ato)dineodymium(III)]

In the crystal structure of the title mixed-ligand coordination polymer, [Nd(2)(C(12)H(6)N(2)O(4))(3)(C(10)H(8)N(2))(2)(H(2)O)(2)](n), the Nd(III) ion is in an octa­hedral coordination environment formed by one water mol­ecule, one chelating 2,2′-bipyridine ligand, and five monodentate carboxyl­ate...

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Detalles Bibliográficos
Autores principales: Tsai, Chia-Jung, Liu, Yen-Hsiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915173/
https://www.ncbi.nlm.nih.gov/pubmed/21200598
http://dx.doi.org/10.1107/S1600536807067396
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author Tsai, Chia-Jung
Liu, Yen-Hsiang
author_facet Tsai, Chia-Jung
Liu, Yen-Hsiang
author_sort Tsai, Chia-Jung
collection PubMed
description In the crystal structure of the title mixed-ligand coordination polymer, [Nd(2)(C(12)H(6)N(2)O(4))(3)(C(10)H(8)N(2))(2)(H(2)O)(2)](n), the Nd(III) ion is in an octa­hedral coordination environment formed by one water mol­ecule, one chelating 2,2′-bipyridine ligand, and five monodentate carboxyl­ate groups. The local coordination polyhedron around the Nd(III) ion is a bicapped trigonal prism. Two Nd(III) centers are bridged by four carboxyl­ate groups to form an Nd(2) dimeric unit; these are further connected by 2,2′-bipyridine-4,4′-dicarboxyl­ate linkers, resulting in a layered coordination network.
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spelling pubmed-29151732010-12-30 Poly[diaqua­bis(2,2′-bipyridine)tris­(μ(4)-2,2′-bipyridine-4,4′-dicarboxyl­ato)dineodymium(III)] Tsai, Chia-Jung Liu, Yen-Hsiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title mixed-ligand coordination polymer, [Nd(2)(C(12)H(6)N(2)O(4))(3)(C(10)H(8)N(2))(2)(H(2)O)(2)](n), the Nd(III) ion is in an octa­hedral coordination environment formed by one water mol­ecule, one chelating 2,2′-bipyridine ligand, and five monodentate carboxyl­ate groups. The local coordination polyhedron around the Nd(III) ion is a bicapped trigonal prism. Two Nd(III) centers are bridged by four carboxyl­ate groups to form an Nd(2) dimeric unit; these are further connected by 2,2′-bipyridine-4,4′-dicarboxyl­ate linkers, resulting in a layered coordination network. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915173/ /pubmed/21200598 http://dx.doi.org/10.1107/S1600536807067396 Text en © Tsai and Liu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tsai, Chia-Jung
Liu, Yen-Hsiang
Poly[diaqua­bis(2,2′-bipyridine)tris­(μ(4)-2,2′-bipyridine-4,4′-dicarboxyl­ato)dineodymium(III)]
title Poly[diaqua­bis(2,2′-bipyridine)tris­(μ(4)-2,2′-bipyridine-4,4′-dicarboxyl­ato)dineodymium(III)]
title_full Poly[diaqua­bis(2,2′-bipyridine)tris­(μ(4)-2,2′-bipyridine-4,4′-dicarboxyl­ato)dineodymium(III)]
title_fullStr Poly[diaqua­bis(2,2′-bipyridine)tris­(μ(4)-2,2′-bipyridine-4,4′-dicarboxyl­ato)dineodymium(III)]
title_full_unstemmed Poly[diaqua­bis(2,2′-bipyridine)tris­(μ(4)-2,2′-bipyridine-4,4′-dicarboxyl­ato)dineodymium(III)]
title_short Poly[diaqua­bis(2,2′-bipyridine)tris­(μ(4)-2,2′-bipyridine-4,4′-dicarboxyl­ato)dineodymium(III)]
title_sort poly[diaqua­bis(2,2′-bipyridine)tris­(μ(4)-2,2′-bipyridine-4,4′-dicarboxyl­ato)dineodymium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915173/
https://www.ncbi.nlm.nih.gov/pubmed/21200598
http://dx.doi.org/10.1107/S1600536807067396
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